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Application of the kinetic isotope effect of tritium to the investigation of the mechanism of hydrogen substitution and transfer reactions

Felix Semenovich Yakushin 1
Felix Semenovich Yakushin
1 Karpov Institute of Physical Chemistry, Moscow
10.1070/RC1962v031n02ABEH001273
Published 30 November 1961
Communication , Volume 31, Issue 2, 123-131
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Yakushin F. S. Application of the kinetic isotope effect of tritium to the investigation of the mechanism of hydrogen substitution and transfer reactions // Russian Chemical Reviews. 1962. Vol. 31. No. 2. pp. 123-131.
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Yakushin F. S. Application of the kinetic isotope effect of tritium to the investigation of the mechanism of hydrogen substitution and transfer reactions // Russian Chemical Reviews. 1962. Vol. 31. No. 2. pp. 123-131.
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TY - JOUR
DO - 10.1070/RC1962v031n02ABEH001273
UR - https://rcr.colab.ws/publications/10.1070/RC1962v031n02ABEH001273
TI - Application of the kinetic isotope effect of tritium to the investigation of the mechanism of hydrogen substitution and transfer reactions
T2 - Russian Chemical Reviews
AU - Yakushin, Felix Semenovich
PY - 1962
DA - 1961/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 123-131
IS - 2
VL - 31
ER -
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@article{1962_Yakushin,
author = {Felix Semenovich Yakushin},
title = {Application of the kinetic isotope effect of tritium to the investigation of the mechanism of hydrogen substitution and transfer reactions},
journal = {Russian Chemical Reviews},
year = {1962},
volume = {31},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1962v031n02ABEH001273},
number = {2},
pages = {123--131},
doi = {10.1070/RC1962v031n02ABEH001273}
}
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Yakushin, Felix Semenovich. “Application of the kinetic isotope effect of tritium to the investigation of the mechanism of hydrogen substitution and transfer reactions.” Russian Chemical Reviews, vol. 31, no. 2, Nov. 1962, pp. 123-131. https://rcr.colab.ws/publications/10.1070/RC1962v031n02ABEH001273.
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Abstract

CONTENTS
I. Introduction 123
II. Theory of the kinetic isotope effect 124
III. Kinetic isotope effect of tritium in electrophilic aromatic substitution reactions and in the acid exchange of hydrogen 125
IV. Kinetic isotope effect of tritium in metallation and hydrogen exchange with a base 128
V. Kinetic isotope effect of tritium in hydrogen transfer reactions 129
VI. Application of the kinetic isotope effect of tritium to the investigation of the mechanism of some other reactions 130