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Mechanisms of the hydrolysis of aromatic sulphonyl chlorides and of alkyl and aryl arenesulphonates

Regina Vikent'evna Vizgert 1
Regina Vikent'evna Vizgert
1 L'vov Polytechnical Institute
10.1070/RC1963v032n01ABEH001289
Published 30 November 1962
Communication , Volume 32, Issue 1, 1-20
17
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Vizgert R. V. Mechanisms of the hydrolysis of aromatic sulphonyl chlorides and of alkyl and aryl arenesulphonates // Russian Chemical Reviews. 1963. Vol. 32. No. 1. pp. 1-20.
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Vizgert R. V. Mechanisms of the hydrolysis of aromatic sulphonyl chlorides and of alkyl and aryl arenesulphonates // Russian Chemical Reviews. 1963. Vol. 32. No. 1. pp. 1-20.
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TY - JOUR
DO - 10.1070/RC1963v032n01ABEH001289
UR - https://rcr.colab.ws/publications/10.1070/RC1963v032n01ABEH001289
TI - Mechanisms of the hydrolysis of aromatic sulphonyl chlorides and of alkyl and aryl arenesulphonates
T2 - Russian Chemical Reviews
AU - Vizgert, Regina Vikent'evna
PY - 1963
DA - 1962/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1-20
IS - 1
VL - 32
ER -
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@article{1963_Vizgert,
author = {Regina Vikent'evna Vizgert},
title = {Mechanisms of the hydrolysis of aromatic sulphonyl chlorides and of alkyl and aryl arenesulphonates},
journal = {Russian Chemical Reviews},
year = {1963},
volume = {32},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1963v032n01ABEH001289},
number = {1},
pages = {1--20},
doi = {10.1070/RC1963v032n01ABEH001289}
}
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Vizgert, Regina Vikent'evna. “Mechanisms of the hydrolysis of aromatic sulphonyl chlorides and of alkyl and aryl arenesulphonates.” Russian Chemical Reviews, vol. 32, no. 1, Nov. 1963, pp. 1-20. https://rcr.colab.ws/publications/10.1070/RC1963v032n01ABEH001289.
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Abstract

CONTENTS
I. Introduction 1
II. Substitution in compounds containing sulphonyl or carbonyl groups 1
III. Site of bond rupture on hydrolysis 2
IV. Influence of catalyst on the mechanism of hydrolysis 3
V. Influence of the polar effects of substituents on the rate of alkaline hydrolysis of esters 5
VI. Influence of solvents 11
VII. Influence of steric factors on the rate and mechanism of the hydrolysis of the chlorides of carboxylic and sulphonic acids 14
VIII. Influence of steric factors on the rate and mechanism of the alkaline and aqueous hydrolysis of aryl sulphonates 15
IX. Correlation of rate constants for the alkaline hydrolysis of arenesulphonic esters with their structure 17