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The chemistry of decaborane and its derivatives

V I Stanko 1
V I Stanko
, 
Yury Andreevich Chapovskii 1
Yury Andreevich Chapovskii
, 
Viktor Aleksandrovich Brattsev 1
Viktor Aleksandrovich Brattsev
, 
Leonid Ivanovich Zakharkin 1
Leonid Ivanovich Zakharkin
1 A. N. Nesmeyanov Institute of Organoelement Compounds, USSR Academy of Sciences, Moscow
10.1070/RC1965v034n06ABEH001455
Published 30 November 1964
Communication , Volume 34, Issue 6, 424-439
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Stanko V. I. et al. The chemistry of decaborane and its derivatives // Russian Chemical Reviews. 1965. Vol. 34. No. 6. pp. 424-439.
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Stanko V. I., Chapovskii Y. A., Brattsev V. A., Zakharkin L. I. The chemistry of decaborane and its derivatives // Russian Chemical Reviews. 1965. Vol. 34. No. 6. pp. 424-439.
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TY - JOUR
DO - 10.1070/RC1965v034n06ABEH001455
UR - https://rcr.colab.ws/publications/10.1070/RC1965v034n06ABEH001455
TI - The chemistry of decaborane and its derivatives
T2 - Russian Chemical Reviews
AU - Stanko, V I
AU - Chapovskii, Yury Andreevich
AU - Brattsev, Viktor Aleksandrovich
AU - Zakharkin, Leonid Ivanovich
PY - 1965
DA - 1964/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 424-439
IS - 6
VL - 34
ER -
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@article{1965_Stanko,
author = {V I Stanko and Yury Andreevich Chapovskii and Viktor Aleksandrovich Brattsev and Leonid Ivanovich Zakharkin},
title = {The chemistry of decaborane and its derivatives},
journal = {Russian Chemical Reviews},
year = {1965},
volume = {34},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1965v034n06ABEH001455},
number = {6},
pages = {424--439},
doi = {10.1070/RC1965v034n06ABEH001455}
}
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Stanko, V. I., et al. “The chemistry of decaborane and its derivatives.” Russian Chemical Reviews, vol. 34, no. 6, Nov. 1965, pp. 424-439. https://rcr.colab.ws/publications/10.1070/RC1965v034n06ABEH001455.
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Abstract

CONTENTS
I. Introduction 424
II. Structure and reactivity of decaborane 425
III. Deuterium exchange in decaborane 427
IV. Pyrolysis of decaborane 428
V. Hydrolysis, alcoholysis, and thiolysis 428
VI. Decaborane as an acid 429
VII. Decaborane Grignard reagents and sodium tridecahydrodecaborate(1-) 429
VIII. Nucleophilic substitution in decaborane 430
IX. Electrophilic substitutions 432
X. The stable anion B10H102- 432
XI. Carboranes 434