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Kinetics and mechanism of the Beckmann rearrangement of alicyclic ketoximes under the catalytic action of sulphuric acid and oleum

Moisey Iosiphovich Vinnik 1
Moisey Iosiphovich Vinnik
, 
N G Zarakhani 1
N G Zarakhani
1 Institute of Chemical Physics of the USSR Academy of Sciences, Moscow
10.1070/RC1967v036n01ABEH001583
Published 30 November 1966
Communication , Volume 36, Issue 1, 51-64
33
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Vinnik M. I., Zarakhani N. G. Kinetics and mechanism of the Beckmann rearrangement of alicyclic ketoximes under the catalytic action of sulphuric acid and oleum // Russian Chemical Reviews. 1967. Vol. 36. No. 1. pp. 51-64.
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Vinnik M. I., Zarakhani N. G. Kinetics and mechanism of the Beckmann rearrangement of alicyclic ketoximes under the catalytic action of sulphuric acid and oleum // Russian Chemical Reviews. 1967. Vol. 36. No. 1. pp. 51-64.
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TY - JOUR
DO - 10.1070/RC1967v036n01ABEH001583
UR - https://rcr.colab.ws/publications/10.1070/RC1967v036n01ABEH001583
TI - Kinetics and mechanism of the Beckmann rearrangement of alicyclic ketoximes under the catalytic action of sulphuric acid and oleum
T2 - Russian Chemical Reviews
AU - Vinnik, Moisey Iosiphovich
AU - Zarakhani, N G
PY - 1967
DA - 1966/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 51-64
IS - 1
VL - 36
ER -
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@article{1967_Vinnik,
author = {Moisey Iosiphovich Vinnik and N G Zarakhani},
title = {Kinetics and mechanism of the Beckmann rearrangement of alicyclic ketoximes under the catalytic action of sulphuric acid and oleum},
journal = {Russian Chemical Reviews},
year = {1967},
volume = {36},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1967v036n01ABEH001583},
number = {1},
pages = {51--64},
doi = {10.1070/RC1967v036n01ABEH001583}
}
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Vinnik, Moisey Iosiphovich, and N G Zarakhani. “Kinetics and mechanism of the Beckmann rearrangement of alicyclic ketoximes under the catalytic action of sulphuric acid and oleum.” Russian Chemical Reviews, vol. 36, no. 1, Nov. 1967, pp. 51-64. https://rcr.colab.ws/publications/10.1070/RC1967v036n01ABEH001583.
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Abstract

CONTENTS
I. Introduction 51
II. Some properties of concentrated aqueous solutions of sulphuric acid 52
III. Some information about the mechanism of ionisation of alicyclic ketoximes in aqueous solutions of strong acids 52
IV. Rate constants of the Beckmann rearrangement of alicyclic ketoximes 53
V. Mechanism of the Beckmann rearrangement of oximes 56
VI. Temperature dependence of the rate constants of the Beckmann rearrangement of alicyclic ketoximes in sulphuric acid and in oleum 62