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Retention of Configuration in Reactions with Opening of an Epoxide Ring

Afanasii Andreevich Akhrem 1
Afanasii Andreevich Akhrem
, 
Aiexsander Makarovich Moiseenkov 1
Aiexsander Makarovich Moiseenkov
, 
V N Dobrynin 1
V N Dobrynin
1 N. D. Zelinskii Institute of Organic Chemistry of the USSR Academy of Sciences, Moscow
10.1070/RC1968v037n06ABEH001652
Published 30 November 1967
Communication , Volume 37, Issue 6, 448-462
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Akhrem A. A., Moiseenkov A. M., Dobrynin V. N. Retention of Configuration in Reactions with Opening of an Epoxide Ring // Russian Chemical Reviews. 1968. Vol. 37. No. 6. pp. 448-462.
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Akhrem A. A., Moiseenkov A. M., Dobrynin V. N. Retention of Configuration in Reactions with Opening of an Epoxide Ring // Russian Chemical Reviews. 1968. Vol. 37. No. 6. pp. 448-462.
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TY - JOUR
DO - 10.1070/RC1968v037n06ABEH001652
UR - https://rcr.colab.ws/publications/10.1070/RC1968v037n06ABEH001652
TI - Retention of Configuration in Reactions with Opening of an Epoxide Ring
T2 - Russian Chemical Reviews
AU - Akhrem, Afanasii Andreevich
AU - Moiseenkov, Aiexsander Makarovich
AU - Dobrynin, V N
PY - 1968
DA - 1967/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 448-462
IS - 6
VL - 37
ER -
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@article{1968_Akhrem,
author = {Afanasii Andreevich Akhrem and Aiexsander Makarovich Moiseenkov and V N Dobrynin},
title = {Retention of Configuration in Reactions with Opening of an Epoxide Ring},
journal = {Russian Chemical Reviews},
year = {1968},
volume = {37},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1968v037n06ABEH001652},
number = {6},
pages = {448--462},
doi = {10.1070/RC1968v037n06ABEH001652}
}
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Akhrem, Afanasii Andreevich, et al. “Retention of Configuration in Reactions with Opening of an Epoxide Ring.” Russian Chemical Reviews, vol. 37, no. 6, Nov. 1968, pp. 448-462. https://rcr.colab.ws/publications/10.1070/RC1968v037n06ABEH001652.
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Abstract

Information on the opening of an epoxide ring with retention of the initial configuration under conditions of catalytic hydrogenation and under the action of various nucleophilic reagents is examined. It is noted that when an electron-donating p- or π-grouping is present in the α position to the epoxide ring the retention of the initial configuration is more probable than its inversion. Bibliography of 182 references.