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Catalysis of Isotope Exchange in Molecular Oxygen and Its Application to the Study of Catalysts

Georgii Konstantinovich Boreskov 1, 2
Georgii Konstantinovich Boreskov
, 
Ludmila Andreevna Kasatkina 1
Ludmila Andreevna Kasatkina
1 Institute of Catalysis Siberian Branch of the Russian Academy of Sciences, Novosibirsk
2 Moscow Chemical Technology Institute
10.1070/RC1968v037n08ABEH001686
Published 30 November 1967
Communication , Volume 37, Issue 8, 613-628
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Boreskov G. K., Kasatkina L. A. Catalysis of Isotope Exchange in Molecular Oxygen and Its Application to the Study of Catalysts // Russian Chemical Reviews. 1968. Vol. 37. No. 8. pp. 613-628.
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Boreskov G. K., Kasatkina L. A. Catalysis of Isotope Exchange in Molecular Oxygen and Its Application to the Study of Catalysts // Russian Chemical Reviews. 1968. Vol. 37. No. 8. pp. 613-628.
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TY - JOUR
DO - 10.1070/RC1968v037n08ABEH001686
UR - https://rcr.colab.ws/publications/10.1070/RC1968v037n08ABEH001686
TI - Catalysis of Isotope Exchange in Molecular Oxygen and Its Application to the Study of Catalysts
T2 - Russian Chemical Reviews
AU - Boreskov, Georgii Konstantinovich
AU - Kasatkina, Ludmila Andreevna
PY - 1968
DA - 1967/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 613-628
IS - 8
VL - 37
ER -
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@article{1968_Boreskov,
author = {Georgii Konstantinovich Boreskov and Ludmila Andreevna Kasatkina},
title = {Catalysis of Isotope Exchange in Molecular Oxygen and Its Application to the Study of Catalysts},
journal = {Russian Chemical Reviews},
year = {1968},
volume = {37},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1968v037n08ABEH001686},
number = {8},
pages = {613--628},
doi = {10.1070/RC1968v037n08ABEH001686}
}
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Boreskov, Georgii Konstantinovich, and Ludmila Andreevna Kasatkina. “Catalysis of Isotope Exchange in Molecular Oxygen and Its Application to the Study of Catalysts.” Russian Chemical Reviews, vol. 37, no. 8, Nov. 1968, pp. 613-628. https://rcr.colab.ws/publications/10.1070/RC1968v037n08ABEH001686.
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Abstract

Problems related to the kinetics and mechanism of isotope exchange in molecular oxygen on solid catalysts are reviewed. Experimental data on the homomolecular exchange of oxygen on oxides and metals are reported. The relationship between the catalytic activity of oxides towards oxygen exchange and their activity towards other oxidation reactions is discussed. It is pointed out that studies of isotope exchange reactions of molecular oxygen should prove useful in elucidating the nature of intermediate entities during the interaction of oxygen with a catalyst surface. The activity towards exchange can be used as a characteristic of general oxygen reactivity, and rules for the choice of oxidation catalysts can be based on it.
The bibliography contains 83 references.