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Dipole Moments and the Structure of π-Complexes of Metals

Alexander Dmitrievich Garnovskii 1
Alexander Dmitrievich Garnovskii
, 
Osip Aleksandrovich Osipov 1
Osip Aleksandrovich Osipov
, 
1 Rostov-on-Don State University
Published 30 November 1967
Communication , Volume 37, Issue 10, 763-778
7
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Garnovskii A. D., Osipov O. A., Minkin V. I. Dipole Moments and the Structure of π-Complexes of Metals // Russian Chemical Reviews. 1968. Vol. 37. No. 10. pp. 763-778.
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Garnovskii A. D., Osipov O. A., Minkin V. I. Dipole Moments and the Structure of π-Complexes of Metals // Russian Chemical Reviews. 1968. Vol. 37. No. 10. pp. 763-778.
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TY - JOUR
DO - 10.1070/RC1968v037n10ABEH001702
UR - https://rcr.colab.ws/publications/10.1070/RC1968v037n10ABEH001702
TI - Dipole Moments and the Structure of π-Complexes of Metals
T2 - Russian Chemical Reviews
AU - Garnovskii, Alexander Dmitrievich
AU - Osipov, Osip Aleksandrovich
AU - Minkin, Vladimir Isaakovich
PY - 1968
DA - 1967/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 763-778
IS - 10
VL - 37
ER -
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@article{1968_Garnovskii,
author = {Alexander Dmitrievich Garnovskii and Osip Aleksandrovich Osipov and Vladimir Isaakovich Minkin},
title = {Dipole Moments and the Structure of π-Complexes of Metals},
journal = {Russian Chemical Reviews},
year = {1968},
volume = {37},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1968v037n10ABEH001702},
number = {10},
pages = {763--778},
doi = {10.1070/RC1968v037n10ABEH001702}
}
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Garnovskii, Alexander Dmitrievich, et al. “Dipole Moments and the Structure of π-Complexes of Metals.” Russian Chemical Reviews, vol. 37, no. 10, Nov. 1968, pp. 763-778. https://rcr.colab.ws/publications/10.1070/RC1968v037n10ABEH001702.
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Abstract

Information on the dipole moments of π-complexes of metals is surveyed and systematised in this article: cyclopentadienyl, arene, alkene, carbonyl, and polymetallic complexes. The possibility of using the dipole moments method for finding the geometric structure of the π-complex molecules, the spatial position of the ligands, and the nature and polarity of the bonds which arise in complex formation has been shown. The results obtained in measurements of dipole moments are compared with data from infrared and NMR spectra. X-ray diffraction, and the chemical properties of the π-complexes. There is a bibliography of 298 references.