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Relative Strength of CH Acids

Aleksandr Isaevich Shatenshtein 1
Aleksandr Isaevich Shatenshtein
, 
I O Shapiro 1
I O Shapiro
1 Karpov Institute of Physical Chemistry, Moscow
Published 30 November 1967
Communication , Volume 37, Issue 11, 845-854
8
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Shatenshtein A. I., Shapiro I. O. Relative Strength of CH Acids // Russian Chemical Reviews. 1968. Vol. 37. No. 11. pp. 845-854.
GOST all authors (up to 50)
Shatenshtein A. I., Shapiro I. O. Relative Strength of CH Acids // Russian Chemical Reviews. 1968. Vol. 37. No. 11. pp. 845-854.
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RIS
TY - JOUR
DO - 10.1070/RC1968v037n11ABEH001709
UR - https://rcr.colab.ws/publications/10.1070/RC1968v037n11ABEH001709
TI - Relative Strength of CH Acids
T2 - Russian Chemical Reviews
AU - Shatenshtein, Aleksandr Isaevich
AU - Shapiro, I O
PY - 1968
DA - 1967/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 845-854
IS - 11
VL - 37
ER -
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@article{1968_Shatenshtein,
author = {Aleksandr Isaevich Shatenshtein and I O Shapiro},
title = {Relative Strength of CH Acids},
journal = {Russian Chemical Reviews},
year = {1968},
volume = {37},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1968v037n11ABEH001709},
number = {11},
pages = {845--854},
doi = {10.1070/RC1968v037n11ABEH001709}
}
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MLA
Shatenshtein, Aleksandr Isaevich, and I O Shapiro. “Relative Strength of CH Acids.” Russian Chemical Reviews, vol. 37, no. 11, Nov. 1968, pp. 845-854. https://rcr.colab.ws/publications/10.1070/RC1968v037n11ABEH001709.
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Abstract

The problem of the differentiating action of solvents on the relative strength of acids is examined from the point of view of the modern theory of acid–base equilibrium, according to which hydrocarbons and their derivatives behave under appropriate conditions as acids. Methods are described for determining the strength of such CH acids. The factors on which the differentiating effect of solvents depends are discussed. The most detailed consideration is given to the question – newly posed in the literature – of the possible causes of the change in the relative kinetic acidity of CH acids produced by solvents, which has been established by measuring the rate of the protophilic isotopic exchange of the hydrogen in them with bases. The bibliography contains 110 references.