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Electron Spin Resonance Spectra, Conformation, and Chemical Properties of Free Radicals in Solid Polymers

Pavel Yur'evich Butyagin 1
Pavel Yur'evich Butyagin
, 
Aleksandra Mikhailovna Dubinskaya 1
Aleksandra Mikhailovna Dubinskaya
, 
Victor Alexandrovich Radtsig 1
Victor Alexandrovich Radtsig
1 Institute of Chemical Physics of the USSR Academy of Sciences, Moscow
10.1070/RC1969v038n04ABEH001742
Published 30 November 1968
Communication , Volume 38, Issue 4, 290-305
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Butyagin P. Y., Dubinskaya A. M., Radtsig V. A. Electron Spin Resonance Spectra, Conformation, and Chemical Properties of Free Radicals in Solid Polymers // Russian Chemical Reviews. 1969. Vol. 38. No. 4. pp. 290-305.
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Butyagin P. Y., Dubinskaya A. M., Radtsig V. A. Electron Spin Resonance Spectra, Conformation, and Chemical Properties of Free Radicals in Solid Polymers // Russian Chemical Reviews. 1969. Vol. 38. No. 4. pp. 290-305.
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TY - JOUR
DO - 10.1070/RC1969v038n04ABEH001742
UR - https://rcr.colab.ws/publications/10.1070/RC1969v038n04ABEH001742
TI - Electron Spin Resonance Spectra, Conformation, and Chemical Properties of Free Radicals in Solid Polymers
T2 - Russian Chemical Reviews
AU - Butyagin, Pavel Yur'evich
AU - Dubinskaya, Aleksandra Mikhailovna
AU - Radtsig, Victor Alexandrovich
PY - 1969
DA - 1968/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 290-305
IS - 4
VL - 38
ER -
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@article{1969_Butyagin,
author = {Pavel Yur'evich Butyagin and Aleksandra Mikhailovna Dubinskaya and Victor Alexandrovich Radtsig},
title = {Electron Spin Resonance Spectra, Conformation, and Chemical Properties of Free Radicals in Solid Polymers},
journal = {Russian Chemical Reviews},
year = {1969},
volume = {38},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1969v038n04ABEH001742},
number = {4},
pages = {290--305},
doi = {10.1070/RC1969v038n04ABEH001742}
}
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Butyagin, Pavel Yur'evich, et al. “Electron Spin Resonance Spectra, Conformation, and Chemical Properties of Free Radicals in Solid Polymers.” Russian Chemical Reviews, vol. 38, no. 4, Nov. 1969, pp. 290-305. https://rcr.colab.ws/publications/10.1070/RC1969v038n04ABEH001742.
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Abstract

The structure and the chemical properties of polymeric radicals having their free valency on a carbon atom in the main chain are surveyed. Most of the information on radicals in solid polymers has been obtained by electron spin resonance. The first part of the review gives a detailed analysis of the hyperfine structure of the e.s.r. spectra, which is closely related to the structure and the conformation of the radicals. The second part deals with the chemical behaviour of polymeric radicals in solid matrices at low temperatures (80–300°K). All the data relate to radicals from polymers of the vinyl series, polyoxides, and polyamides. A list of 112 references is given.