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Study of the Mechanisms of Heterogeneous-catalytic Reactions by the Method of Labelled Molecules (labelled with 14C)

Yu I Derbentsev 1
Yu I Derbentsev
, 
Georgii Vacheevich Isagulyants 1
Georgii Vacheevich Isagulyants
1 N. D. Zelinskii Institute of Organic Chemistry of the USSR Academy of Sciences, Moscow
10.1070/RC1969v038n09ABEH001827
Published 30 November 1968
Communication , Volume 38, Issue 9, 714-727
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Derbentsev Yu. I., Isagulyants G. V. Study of the Mechanisms of Heterogeneous-catalytic Reactions by the Method of Labelled Molecules (labelled with 14C) // Russian Chemical Reviews. 1969. Vol. 38. No. 9. pp. 714-727.
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Derbentsev Yu. I., Isagulyants G. V. Study of the Mechanisms of Heterogeneous-catalytic Reactions by the Method of Labelled Molecules (labelled with 14C) // Russian Chemical Reviews. 1969. Vol. 38. No. 9. pp. 714-727.
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TY - JOUR
DO - 10.1070/RC1969v038n09ABEH001827
UR - https://rcr.colab.ws/publications/10.1070/RC1969v038n09ABEH001827
TI - Study of the Mechanisms of Heterogeneous-catalytic Reactions by the Method of Labelled Molecules (labelled with 14C)
T2 - Russian Chemical Reviews
AU - Derbentsev, Yu I
AU - Isagulyants, Georgii Vacheevich
PY - 1969
DA - 1968/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 714-727
IS - 9
VL - 38
ER -
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@article{1969_Derbentsev,
author = {Yu I Derbentsev and Georgii Vacheevich Isagulyants},
title = {Study of the Mechanisms of Heterogeneous-catalytic Reactions by the Method of Labelled Molecules (labelled with 14C)},
journal = {Russian Chemical Reviews},
year = {1969},
volume = {38},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1969v038n09ABEH001827},
number = {9},
pages = {714--727},
doi = {10.1070/RC1969v038n09ABEH001827}
}
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Derbentsev, Yu. I., and Georgii Vacheevich Isagulyants. “Study of the Mechanisms of Heterogeneous-catalytic Reactions by the Method of Labelled Molecules (labelled with 14C).” Russian Chemical Reviews, vol. 38, no. 9, Nov. 1969, pp. 714-727. https://rcr.colab.ws/publications/10.1070/RC1969v038n09ABEH001827.
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Abstract

The present review differentiates between the method of labelled atoms (the LA method) and the method of labelled molecules (the LM method). Unlike the LA method, in which an experimental study is made of the distribution of the isotopic tracer over various positions in the molecules of the starting materials and reaction products, the LM method involves the study of the distribution of the isotopic tracer between the molecules of different substances. The basic equations of the LM method for integral and differential reactors are given, and literature on the application of the LM method with the 14C isotope to study the mechanisms of heterogeneous-catalytic reactions is reviewed. The bibliography contains 163 references.