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Effect of Electron-donor Solvents on the Reactivity of Lithium Alkyls

Evgeniy Aleksandrovich Kovrizhnykh 1
Evgeniy Aleksandrovich Kovrizhnykh
, 
Aleksandr Isaevich Shatenshtein 1
Aleksandr Isaevich Shatenshtein
1 Karpov Institute of Physical Chemistry, Moscow
10.1070/RC1969v038n10ABEH001854
Published 30 November 1968
Communication , Volume 38, Issue 10, 840-849
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Kovrizhnykh E. A., Shatenshtein A. I. Effect of Electron-donor Solvents on the Reactivity of Lithium Alkyls // Russian Chemical Reviews. 1969. Vol. 38. No. 10. pp. 840-849.
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Kovrizhnykh E. A., Shatenshtein A. I. Effect of Electron-donor Solvents on the Reactivity of Lithium Alkyls // Russian Chemical Reviews. 1969. Vol. 38. No. 10. pp. 840-849.
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TY - JOUR
DO - 10.1070/RC1969v038n10ABEH001854
UR - https://rcr.colab.ws/publications/10.1070/RC1969v038n10ABEH001854
TI - Effect of Electron-donor Solvents on the Reactivity of Lithium Alkyls
T2 - Russian Chemical Reviews
AU - Kovrizhnykh, Evgeniy Aleksandrovich
AU - Shatenshtein, Aleksandr Isaevich
PY - 1969
DA - 1968/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 840-849
IS - 10
VL - 38
ER -
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@article{1969_Kovrizhnykh,
author = {Evgeniy Aleksandrovich Kovrizhnykh and Aleksandr Isaevich Shatenshtein},
title = {Effect of Electron-donor Solvents on the Reactivity of Lithium Alkyls},
journal = {Russian Chemical Reviews},
year = {1969},
volume = {38},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1969v038n10ABEH001854},
number = {10},
pages = {840--849},
doi = {10.1070/RC1969v038n10ABEH001854}
}
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Kovrizhnykh, Evgeniy Aleksandrovich, and Aleksandr Isaevich Shatenshtein. “Effect of Electron-donor Solvents on the Reactivity of Lithium Alkyls.” Russian Chemical Reviews, vol. 38, no. 10, Nov. 1969, pp. 840-849. https://rcr.colab.ws/publications/10.1070/RC1969v038n10ABEH001854.
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Abstract

The causes of, and the relations governing, the acceleration of reactions involving lithium alkyls by electron-donor solvents are discussed. The kinetic effect is due to a change in the polarity of the C–Li bond in consequence of the formation of complexes (of the donor–acceptor type) of the lithium alkyl and the solvent and a change in the state of lithium alkyl in solution.
The bibliography includes 115 references.