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The Structure of Aliphatic Diazo-compounds and Their Isomers

Oleg Petrovich Studzinskii 1
Oleg Petrovich Studzinskii
, 
Irina Kirillovna Korobitsyna 1
Irina Kirillovna Korobitsyna
1 Leningrad State University
10.1070/RC1970v039n10ABEH002046
Published 30 November 1969
Communication , Volume 39, Issue 10, 834-843
9
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Studzinskii O. P., Korobitsyna I. K. The Structure of Aliphatic Diazo-compounds and Their Isomers // Russian Chemical Reviews. 1970. Vol. 39. No. 10. pp. 834-843.
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Studzinskii O. P., Korobitsyna I. K. The Structure of Aliphatic Diazo-compounds and Their Isomers // Russian Chemical Reviews. 1970. Vol. 39. No. 10. pp. 834-843.
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TY - JOUR
DO - 10.1070/RC1970v039n10ABEH002046
UR - https://rcr.colab.ws/publications/10.1070/RC1970v039n10ABEH002046
TI - The Structure of Aliphatic Diazo-compounds and Their Isomers
T2 - Russian Chemical Reviews
AU - Studzinskii, Oleg Petrovich
AU - Korobitsyna, Irina Kirillovna
PY - 1970
DA - 1969/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 834-843
IS - 10
VL - 39
ER -
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@article{1970_Studzinskii,
author = {Oleg Petrovich Studzinskii and Irina Kirillovna Korobitsyna},
title = {The Structure of Aliphatic Diazo-compounds and Their Isomers},
journal = {Russian Chemical Reviews},
year = {1970},
volume = {39},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1970v039n10ABEH002046},
number = {10},
pages = {834--843},
doi = {10.1070/RC1970v039n10ABEH002046}
}
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Studzinskii, Oleg Petrovich, and Irina Kirillovna Korobitsyna. “The Structure of Aliphatic Diazo-compounds and Their Isomers.” Russian Chemical Reviews, vol. 39, no. 10, Nov. 1970, pp. 834-843. https://rcr.colab.ws/publications/10.1070/RC1970v039n10ABEH002046.
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Abstract

The review describes the modern concepts concerning the electronic fine structure of aliphatic diazo-compounds based on experimental data (from infrared, ultraviolet, and PMR spectroscopy) and also quantum-mechanical calculations by the LCAO-MO method. These concepts explain many chemical properties of diazoalkanes and sometimes make it possible to predict them. Apart from "classical" aliphatic diazo-compounds, the structures and properties of the isomers – linear (N-isocyanamine) and cyclic (diazirines) – are considered.
The bibliography comprises 99 references.