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Structural and Steric Factors Determining the Rate of Autoxidation of α-Methylene Groups in Alkylarenes and Alkenes

Valentin Vasil'evich Voronenkov 1
Valentin Vasil'evich Voronenkov
, 
A N Vinogradov 2
A N Vinogradov
, 
Vladimir Aleksandrovich Belyaev 2
Vladimir Aleksandrovich Belyaev
1 Yaroslavl Institute of Technology
2 Research Institute "Yarsintez", Yaroslavl'
10.1070/RC1970v039n11ABEH002053
Published 30 November 1969
Communication , Volume 39, Issue 11, 944-952
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Voronenkov V. V., Vinogradov A. N., Belyaev V. A. Structural and Steric Factors Determining the Rate of Autoxidation of α-Methylene Groups in Alkylarenes and Alkenes // Russian Chemical Reviews. 1970. Vol. 39. No. 11. pp. 944-952.
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Voronenkov V. V., Vinogradov A. N., Belyaev V. A. Structural and Steric Factors Determining the Rate of Autoxidation of α-Methylene Groups in Alkylarenes and Alkenes // Russian Chemical Reviews. 1970. Vol. 39. No. 11. pp. 944-952.
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TY - JOUR
DO - 10.1070/RC1970v039n11ABEH002053
UR - https://rcr.colab.ws/publications/10.1070/RC1970v039n11ABEH002053
TI - Structural and Steric Factors Determining the Rate of Autoxidation of α-Methylene Groups in Alkylarenes and Alkenes
T2 - Russian Chemical Reviews
AU - Voronenkov, Valentin Vasil'evich
AU - Vinogradov, A N
AU - Belyaev, Vladimir Aleksandrovich
PY - 1970
DA - 1969/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 944-952
IS - 11
VL - 39
ER -
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@article{1970_Voronenkov,
author = {Valentin Vasil'evich Voronenkov and A N Vinogradov and Vladimir Aleksandrovich Belyaev},
title = {Structural and Steric Factors Determining the Rate of Autoxidation of α-Methylene Groups in Alkylarenes and Alkenes},
journal = {Russian Chemical Reviews},
year = {1970},
volume = {39},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1970v039n11ABEH002053},
number = {11},
pages = {944--952},
doi = {10.1070/RC1970v039n11ABEH002053}
}
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Voronenkov, Valentin Vasil'evich, et al. “Structural and Steric Factors Determining the Rate of Autoxidation of α-Methylene Groups in Alkylarenes and Alkenes.” Russian Chemical Reviews, vol. 39, no. 11, Nov. 1970, pp. 944-952. https://rcr.colab.ws/publications/10.1070/RC1970v039n11ABEH002053.
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Abstract

Data on structural and steric effects in the autoxidation of alkylarenes and alkenes are summarised. Special attention is paid to the effect of steric hindrance on the rate of oxidation of an α-CH bond in various hydrocarbons – alkylbenzenes, alkylnaphthalenes, alkenes, alkylindanes, and tetrahydronaphthalenes – and data are given on the relation between their refractions, ultraviolet spectra, and rate of oxidation. The role of the molecular conformation of the hydrocarbons in the conjugation of single bonds is demonstrated, together with the effect of this conjugation on the rate of autoxidation of the α-CH bond.
A list of 91 references is included.