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Correlation Equations in Free-radical Reactions

Igor' Borisovich Afanas'ev 1
Igor' Borisovich Afanas'ev
1 NII Vitamins, Moscow
10.1070/RC1971v040n03ABEH001914
Published 30 November 1970
Communication , Volume 40, Issue 3, 216-232
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Afanas'ev I. B. Correlation Equations in Free-radical Reactions // Russian Chemical Reviews. 1971. Vol. 40. No. 3. pp. 216-232.
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Afanas'ev I. B. Correlation Equations in Free-radical Reactions // Russian Chemical Reviews. 1971. Vol. 40. No. 3. pp. 216-232.
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TY - JOUR
DO - 10.1070/RC1971v040n03ABEH001914
UR - https://rcr.colab.ws/publications/10.1070/RC1971v040n03ABEH001914
TI - Correlation Equations in Free-radical Reactions
T2 - Russian Chemical Reviews
AU - Afanas'ev, Igor' Borisovich
PY - 1971
DA - 1970/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 216-232
IS - 3
VL - 40
ER -
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@article{1971_Afanas'ev,
author = {Igor' Borisovich Afanas'ev},
title = {Correlation Equations in Free-radical Reactions},
journal = {Russian Chemical Reviews},
year = {1971},
volume = {40},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1971v040n03ABEH001914},
number = {3},
pages = {216--232},
doi = {10.1070/RC1971v040n03ABEH001914}
}
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Afanas'ev, Igor' Borisovich. “Correlation Equations in Free-radical Reactions.” Russian Chemical Reviews, vol. 40, no. 3, Nov. 1971, pp. 216-232. https://rcr.colab.ws/publications/10.1070/RC1971v040n03ABEH001914.
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Abstract

This review deals with the methods of correlation analysis which have been applied to studies of the kinetics of free-radical reactions. It discusses the use of the Hammett and the Taft equation, of the Alfrey–Price scheme, of the Bamford equation, and also the correlations with quantum-mechanical parameters and various additive empirical methods. Polar and resonance effects in free-radical reactions are quantitatively separated by a two-parameter scheme based on the Taft equation. The relationship between the structure of the transition state and the reactivity of the free radicals is considered.
265 references.