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The Chemistry of Acyl Radicals in Solution

Maksim Gavrilovich Vinogradov 1
Maksim Gavrilovich Vinogradov
, 
Gennady Ivanovich Nikishin 1
Gennady Ivanovich Nikishin
1 N. D. Zelinskii Institute of Organic Chemistry of the USSR Academy of Sciences, Moscow
10.1070/RC1971v040n11ABEH001983
Published 30 November 1970
Communication , Volume 40, Issue 11, 916-932
23
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Vinogradov M. G., Nikishin G. I. The Chemistry of Acyl Radicals in Solution // Russian Chemical Reviews. 1971. Vol. 40. No. 11. pp. 916-932.
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Vinogradov M. G., Nikishin G. I. The Chemistry of Acyl Radicals in Solution // Russian Chemical Reviews. 1971. Vol. 40. No. 11. pp. 916-932.
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TY - JOUR
DO - 10.1070/RC1971v040n11ABEH001983
UR - https://rcr.colab.ws/publications/10.1070/RC1971v040n11ABEH001983
TI - The Chemistry of Acyl Radicals in Solution
T2 - Russian Chemical Reviews
AU - Vinogradov, Maksim Gavrilovich
AU - Nikishin, Gennady Ivanovich
PY - 1971
DA - 1970/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 916-932
IS - 11
VL - 40
ER -
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@article{1971_Vinogradov,
author = {Maksim Gavrilovich Vinogradov and Gennady Ivanovich Nikishin},
title = {The Chemistry of Acyl Radicals in Solution},
journal = {Russian Chemical Reviews},
year = {1971},
volume = {40},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1971v040n11ABEH001983},
number = {11},
pages = {916--932},
doi = {10.1070/RC1971v040n11ABEH001983}
}
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Vinogradov, Maksim Gavrilovich, and Gennady Ivanovich Nikishin. “The Chemistry of Acyl Radicals in Solution.” Russian Chemical Reviews, vol. 40, no. 11, Nov. 1971, pp. 916-932. https://rcr.colab.ws/publications/10.1070/RC1971v040n11ABEH001983.
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Abstract

The available methods for the generation of acyl radicals and their reactions in solutions are reviewed. The effect of stabilising and polar factors on the reactivity of acyl radicals and the mode of their addition to unsaturated molecules are discussed. The characteristics of the reactions involving acyl radicals, initiated by various methods (by peroxides, ultraviolet light, γ-irradiation, etc.) have been examined. Much attention has been devoted to the role of acyl radicals in chain processes constituting the basis of new methods for the synthesis of carbonyl compounds.
The bibliography includes 266 references.