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Determination of the Number of Active Centres and Growth Rate Constants in the Catalytic Polymerisation of α-Alkenes

Yurii Ivanovich Ermakov 1
Yurii Ivanovich Ermakov
, 
Vladimir Aleksandrovich Zakharov 1
Vladimir Aleksandrovich Zakharov
1 Institute of Catalysis Siberian Branch of the Russian Academy of Sciences, Novosibirsk
10.1070/RC1972v041n03ABEH002039
Published 30 November 1971
Communication , Volume 41, Issue 3, 203-215
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Ermakov Y. I., Zakharov V. A. Determination of the Number of Active Centres and Growth Rate Constants in the Catalytic Polymerisation of α-Alkenes // Russian Chemical Reviews. 1972. Vol. 41. No. 3. pp. 203-215.
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Ermakov Y. I., Zakharov V. A. Determination of the Number of Active Centres and Growth Rate Constants in the Catalytic Polymerisation of α-Alkenes // Russian Chemical Reviews. 1972. Vol. 41. No. 3. pp. 203-215.
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TY - JOUR
DO - 10.1070/RC1972v041n03ABEH002039
UR - https://rcr.colab.ws/publications/10.1070/RC1972v041n03ABEH002039
TI - Determination of the Number of Active Centres and Growth Rate Constants in the Catalytic Polymerisation of α-Alkenes
T2 - Russian Chemical Reviews
AU - Ermakov, Yurii Ivanovich
AU - Zakharov, Vladimir Aleksandrovich
PY - 1972
DA - 1971/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 203-215
IS - 3
VL - 41
ER -
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@article{1972_Ermakov,
author = {Yurii Ivanovich Ermakov and Vladimir Aleksandrovich Zakharov},
title = {Determination of the Number of Active Centres and Growth Rate Constants in the Catalytic Polymerisation of α-Alkenes},
journal = {Russian Chemical Reviews},
year = {1972},
volume = {41},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1972v041n03ABEH002039},
number = {3},
pages = {203--215},
doi = {10.1070/RC1972v041n03ABEH002039}
}
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Ermakov, Yurii Ivanovich, and Vladimir Aleksandrovich Zakharov. “Determination of the Number of Active Centres and Growth Rate Constants in the Catalytic Polymerisation of α-Alkenes.” Russian Chemical Reviews, vol. 41, no. 3, Nov. 1972, pp. 203-215. https://rcr.colab.ws/publications/10.1070/RC1972v041n03ABEH002039.
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Abstract

The reliability of different methods for determining the number of active centres (n) and calculating the growth rate constants (kg) in the catalytic polymerisation of α-alkenes is discussed. The values of n and kg obtained for different catalytic systems are given. Information on the dependence of the number of growth centres and the rate constants of the separate steps (primarily the growth rate constants) on the composition of the catalyst, its method of preparation, and the conditions of polymerisation can yield important conclusions regarding the mechanism of polymerisation and the composition of the active centres.
The bibliography contains 113 references.