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Structure and Properties of Oxide Halides of Phosphorus and Certain Transition Elements

T N Naumova 1
T N Naumova
, 
T S Vvedenskaya 1
T S Vvedenskaya
, 
Boris Dmitrievich Stepin 1
Boris Dmitrievich Stepin
1 All-Union Scientific-Research Institute for Chemical Agents and Especially Pure Chemical Substance, Moscow
10.1070/RC1972v041n06ABEH002070
Published 30 November 1971
Communication , Volume 41, Issue 6, 485-494
6
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Naumova T. N., Vvedenskaya T. S., Stepin B. D. Structure and Properties of Oxide Halides of Phosphorus and Certain Transition Elements // Russian Chemical Reviews. 1972. Vol. 41. No. 6. pp. 485-494.
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Naumova T. N., Vvedenskaya T. S., Stepin B. D. Structure and Properties of Oxide Halides of Phosphorus and Certain Transition Elements // Russian Chemical Reviews. 1972. Vol. 41. No. 6. pp. 485-494.
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TY - JOUR
DO - 10.1070/RC1972v041n06ABEH002070
UR - https://rcr.colab.ws/publications/10.1070/RC1972v041n06ABEH002070
TI - Structure and Properties of Oxide Halides of Phosphorus and Certain Transition Elements
T2 - Russian Chemical Reviews
AU - Naumova, T N
AU - Vvedenskaya, T S
AU - Stepin, Boris Dmitrievich
PY - 1972
DA - 1971/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 485-494
IS - 6
VL - 41
ER -
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@article{1972_Naumova,
author = {T N Naumova and T S Vvedenskaya and Boris Dmitrievich Stepin},
title = {Structure and Properties of Oxide Halides of Phosphorus and Certain Transition Elements},
journal = {Russian Chemical Reviews},
year = {1972},
volume = {41},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1972v041n06ABEH002070},
number = {6},
pages = {485--494},
doi = {10.1070/RC1972v041n06ABEH002070}
}
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Naumova, T. N., et al. “Structure and Properties of Oxide Halides of Phosphorus and Certain Transition Elements.” Russian Chemical Reviews, vol. 41, no. 6, Nov. 1972, pp. 485-494. https://rcr.colab.ws/publications/10.1070/RC1972v041n06ABEH002070.
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Abstract

Published information is presented on the structure and the properties of phosphoryl compounds and certain others containing oxo-groups. Modern views on the structure of the phosphoryl group are related to the presence of a σ-bond and also to dπ–pπ interaction between the orbitals of the phosphorus and oxygen atoms; this type of interaction is observed also at other bonds involving phosphorus (P–Hal). Compounds containing oxo-groups exhibit donor properties, forming complexes with acceptor molecules. The general properties of donor–acceptor complex compounds are discussed. A list of 196 references is included.