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Stereochemistry of Free-radical Additions in the Bicyclo[2.2.1]heptene and Bicyclo[2.2.1]heptadiene Series

V A Azovskaya 1
V A Azovskaya
, 
Elena Nikolaevna Prilezhaeva 1
Elena Nikolaevna Prilezhaeva
1 N. D. Zelinskii Institute of Organic Chemistry of the USSR Academy of Sciences, Moscow
10.1070/RC1972v041n06ABEH002072
Published 30 November 1971
Communication , Volume 41, Issue 6, 516-528
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Azovskaya V. A., Prilezhaeva E. N. Stereochemistry of Free-radical Additions in the Bicyclo[2.2.1]heptene and Bicyclo[2.2.1]heptadiene Series // Russian Chemical Reviews. 1972. Vol. 41. No. 6. pp. 516-528.
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Azovskaya V. A., Prilezhaeva E. N. Stereochemistry of Free-radical Additions in the Bicyclo[2.2.1]heptene and Bicyclo[2.2.1]heptadiene Series // Russian Chemical Reviews. 1972. Vol. 41. No. 6. pp. 516-528.
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TY - JOUR
DO - 10.1070/RC1972v041n06ABEH002072
UR - https://rcr.colab.ws/publications/10.1070/RC1972v041n06ABEH002072
TI - Stereochemistry of Free-radical Additions in the Bicyclo[2.2.1]heptene and Bicyclo[2.2.1]heptadiene Series
T2 - Russian Chemical Reviews
AU - Azovskaya, V A
AU - Prilezhaeva, Elena Nikolaevna
PY - 1972
DA - 1971/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 516-528
IS - 6
VL - 41
ER -
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@article{1972_Azovskaya,
author = {V A Azovskaya and Elena Nikolaevna Prilezhaeva},
title = {Stereochemistry of Free-radical Additions in the Bicyclo[2.2.1]heptene and Bicyclo[2.2.1]heptadiene Series},
journal = {Russian Chemical Reviews},
year = {1972},
volume = {41},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1972v041n06ABEH002072},
number = {6},
pages = {516--528},
doi = {10.1070/RC1972v041n06ABEH002072}
}
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Azovskaya, V. A., and Elena Nikolaevna Prilezhaeva. “Stereochemistry of Free-radical Additions in the Bicyclo[2.2.1]heptene and Bicyclo[2.2.1]heptadiene Series.” Russian Chemical Reviews, vol. 41, no. 6, Nov. 1972, pp. 516-528. https://rcr.colab.ws/publications/10.1070/RC1972v041n06ABEH002072.
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Abstract

The stereochemistry of free-radical additions to norbornene and norbornadiene systems is examined. The dependence of the direction of radical attack on the degree of substitution of the bicyclene, and on the position and steric and electronic effects of the substituents is discussed. A mechanism of radical rearrangement of the corresponding norbornene radicals is considered.
109 references.