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Intramolecular Rearrangements of Hydrocarbon Radicals in the Gas Phase

Aleksandr Davidovich Stepukhovich
Aleksandr Davidovich Stepukhovich
, 
V I Babayan
V I Babayan
10.1070/RC1972v041n09ABEH002090
Published 30 November 1971
Communication , Volume 41, Issue 9, 750-758
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Stepukhovich A. D., Babayan V. I. Intramolecular Rearrangements of Hydrocarbon Radicals in the Gas Phase // Russian Chemical Reviews. 1972. Vol. 41. No. 9. pp. 750-758.
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Stepukhovich A. D., Babayan V. I. Intramolecular Rearrangements of Hydrocarbon Radicals in the Gas Phase // Russian Chemical Reviews. 1972. Vol. 41. No. 9. pp. 750-758.
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TY - JOUR
DO - 10.1070/RC1972v041n09ABEH002090
UR - https://rcr.colab.ws/publications/10.1070/RC1972v041n09ABEH002090
TI - Intramolecular Rearrangements of Hydrocarbon Radicals in the Gas Phase
T2 - Russian Chemical Reviews
AU - Stepukhovich, Aleksandr Davidovich
AU - Babayan, V I
PY - 1972
DA - 1971/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 750-758
IS - 9
VL - 41
ER -
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@article{1972_Stepukhovich,
author = {Aleksandr Davidovich Stepukhovich and V I Babayan},
title = {Intramolecular Rearrangements of Hydrocarbon Radicals in the Gas Phase},
journal = {Russian Chemical Reviews},
year = {1972},
volume = {41},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1972v041n09ABEH002090},
number = {9},
pages = {750--758},
doi = {10.1070/RC1972v041n09ABEH002090}
}
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Stepukhovich, Aleksandr Davidovich, and V I Babayan. “Intramolecular Rearrangements of Hydrocarbon Radicals in the Gas Phase.” Russian Chemical Reviews, vol. 41, no. 9, Nov. 1972, pp. 750-758. https://rcr.colab.ws/publications/10.1070/RC1972v041n09ABEH002090.
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Abstract

The review deals with the rearrangements of alkyl radicals occurring in various gas-phase processes. Intramolecular isomerisations involving the migration of a hydrogen atom with formation of three-, four-, five-, and six-membered transition states are examined. The possibility of the isomerisation of small alkyl radicals (ethyl and propyl radicals) and of the transfer of hydrogen to a neighbouring carbon atom in long-chain radicals is discussed. The process mechanism is considered. The bibliography includes 82 references.

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