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Reaction Mechanisms of the Direct Epoxidation of Alkenes in the Liquid Phase

Dmitrii Ivanovich Metelitsa 1
Dmitrii Ivanovich Metelitsa
1 Institute of Chemical Physics of the USSR Academy of Sciences, Moscow
10.1070/RC1972v041n10ABEH002095
Published 30 November 1971
Communication , Volume 41, Issue 10, 807-821
44
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Metelitsa D. I. Reaction Mechanisms of the Direct Epoxidation of Alkenes in the Liquid Phase // Russian Chemical Reviews. 1972. Vol. 41. No. 10. pp. 807-821.
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Metelitsa D. I. Reaction Mechanisms of the Direct Epoxidation of Alkenes in the Liquid Phase // Russian Chemical Reviews. 1972. Vol. 41. No. 10. pp. 807-821.
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TY - JOUR
DO - 10.1070/RC1972v041n10ABEH002095
UR - https://rcr.colab.ws/publications/10.1070/RC1972v041n10ABEH002095
TI - Reaction Mechanisms of the Direct Epoxidation of Alkenes in the Liquid Phase
T2 - Russian Chemical Reviews
AU - Metelitsa, Dmitrii Ivanovich
PY - 1972
DA - 1971/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 807-821
IS - 10
VL - 41
ER -
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@article{1972_Metelitsa,
author = {Dmitrii Ivanovich Metelitsa},
title = {Reaction Mechanisms of the Direct Epoxidation of Alkenes in the Liquid Phase},
journal = {Russian Chemical Reviews},
year = {1972},
volume = {41},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1972v041n10ABEH002095},
number = {10},
pages = {807--821},
doi = {10.1070/RC1972v041n10ABEH002095}
}
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Metelitsa, Dmitrii Ivanovich. “Reaction Mechanisms of the Direct Epoxidation of Alkenes in the Liquid Phase.” Russian Chemical Reviews, vol. 41, no. 10, Nov. 1972, pp. 807-821. https://rcr.colab.ws/publications/10.1070/RC1972v041n10ABEH002095.
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Abstract

Reaction mechanisms for the liquid-phase epoxidation of alkenes are reviewed critically: the classical Prilezhaev reaction, catalytic epoxidation with participation of hydrogen peroxide and of organic hydroperoxides, reactions for the production of alkene oxides in the oxidation of unsaturated hydrocarbons, reaction of a combined oxidation of alkenes with aldehydes. The mechanism and prospects of the catalysed oxidation with oxygen of alkenes to epoxides are discussed in detail.
150 references.