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Polarographic Behaviour of Cobalt(II), Nickel(II), and Iron(II)

V N Pavlov 1
V N Pavlov
, 
Vladimir Vladimirovich Bondar' 1
Vladimir Vladimirovich Bondar'
1 VINITI, Dep. "Chemistry", Moscow
10.1070/RC1973v042n06ABEH002631
Published 30 November 1972
Communication , Volume 42, Issue 6, 438-451
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Pavlov V. N., Bondar' V. V. Polarographic Behaviour of Cobalt(II), Nickel(II), and Iron(II) // Russian Chemical Reviews. 1973. Vol. 42. No. 6. pp. 438-451.
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Pavlov V. N., Bondar' V. V. Polarographic Behaviour of Cobalt(II), Nickel(II), and Iron(II) // Russian Chemical Reviews. 1973. Vol. 42. No. 6. pp. 438-451.
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TY - JOUR
DO - 10.1070/RC1973v042n06ABEH002631
UR - https://rcr.colab.ws/publications/10.1070/RC1973v042n06ABEH002631
TI - Polarographic Behaviour of Cobalt(II), Nickel(II), and Iron(II)
T2 - Russian Chemical Reviews
AU - Pavlov, V N
AU - Bondar', Vladimir Vladimirovich
PY - 1973
DA - 1972/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 438-451
IS - 6
VL - 42
ER -
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@article{1973_Pavlov,
author = {V N Pavlov and Vladimir Vladimirovich Bondar'},
title = {Polarographic Behaviour of Cobalt(II), Nickel(II), and Iron(II)},
journal = {Russian Chemical Reviews},
year = {1973},
volume = {42},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1973v042n06ABEH002631},
number = {6},
pages = {438--451},
doi = {10.1070/RC1973v042n06ABEH002631}
}
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Pavlov, V. N., and Vladimir Vladimirovich Bondar'. “Polarographic Behaviour of Cobalt(II), Nickel(II), and Iron(II).” Russian Chemical Reviews, vol. 42, no. 6, Nov. 1973, pp. 438-451. https://rcr.colab.ws/publications/10.1070/RC1973v042n06ABEH002631.
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Abstract

The kinetics and mechanism of reduction of bivalent metals of the iron group at a mercury dropping electrode are examined. The effect of the pH, organic solvent, structure of the double layer, and adsorption of the depolariser on the half-wave potential and limiting currents of the wave for the reduction of cobalt(II), nickel(II), and iron(II) complexes is described. The role of complex formation in depressing the overpotential for the discharge of these metals is considered in detail. Various viewpoints are presented on the mechanism of formation of the catalytic waves of hydrogen, which appear when doubly-charged ions of these metals and various organic substances are present in the solution simultaneously.
There is a bibliography of 93 references.