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System of Retention Indices and Its Physicochemical Application

Rimma Vladimirovna Golovnya 1
Rimma Vladimirovna Golovnya
, 
Yu N Arsen'ev 1
Yu N Arsen'ev
1 A. N. Nesmeyanov Institute of Organoelement Compounds, USSR Academy of Sciences, Moscow
10.1070/RC1973v042n12ABEH002783
Published 30 November 1972
Communication , Volume 42, Issue 12, 1034-1047
11
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Golovnya R. V., Arsen'ev Yu. N. System of Retention Indices and Its Physicochemical Application // Russian Chemical Reviews. 1973. Vol. 42. No. 12. pp. 1034-1047.
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Golovnya R. V., Arsen'ev Yu. N. System of Retention Indices and Its Physicochemical Application // Russian Chemical Reviews. 1973. Vol. 42. No. 12. pp. 1034-1047.
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TY - JOUR
DO - 10.1070/RC1973v042n12ABEH002783
UR - https://rcr.colab.ws/publications/10.1070/RC1973v042n12ABEH002783
TI - System of Retention Indices and Its Physicochemical Application
T2 - Russian Chemical Reviews
AU - Golovnya, Rimma Vladimirovna
AU - Arsen'ev, Yu N
PY - 1973
DA - 1972/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1034-1047
IS - 12
VL - 42
ER -
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@article{1973_Golovnya,
author = {Rimma Vladimirovna Golovnya and Yu N Arsen'ev},
title = {System of Retention Indices and Its Physicochemical Application},
journal = {Russian Chemical Reviews},
year = {1973},
volume = {42},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1973v042n12ABEH002783},
number = {12},
pages = {1034--1047},
doi = {10.1070/RC1973v042n12ABEH002783}
}
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Golovnya, Rimma Vladimirovna, and Yu N Arsen'ev. “System of Retention Indices and Its Physicochemical Application.” Russian Chemical Reviews, vol. 42, no. 12, Nov. 1973, pp. 1034-1047. https://rcr.colab.ws/publications/10.1070/RC1973v042n12ABEH002783.
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Abstract

The system of retention indices widely used in gas chromatography is reviewed. Methods of calculating indices are examined, their accuracy and reproducibility, and the effect on the index of parameters of the gas-chromatographic experiment (temperature, pressure, velocity of carrier gas, and quantity of stationary phase in the column). Systems resembling retention indices are described, problems of polarity, selectivity, and effectiveness of separation are discussed, and the physicochemical application of indices to calculate various thermodynamic functions is considered. A list of 252 references is included.