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Catalysis of Symmetry-disallowed Reactions

Veronika Iosifovna Labunskaya 1
Veronika Iosifovna Labunskaya
, 
Asya Dmitrievna Shebaldova 1
Asya Dmitrievna Shebaldova
, 
Mikhail L'vovich Khidekel' 2
Mikhail L'vovich Khidekel'
1 Saratov State University named after N. G. Chernyshevsky
2 Institute of Chemical Physics of the USSR Academy of Sciences, Moscow
10.1070/RC1974v043n01ABEH001785
Published 30 November 1973
Communication , Volume 43, Issue 1, 1-16
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Labunskaya V. I., Shebaldova A. D., Khidekel' M. L. Catalysis of Symmetry-disallowed Reactions // Russian Chemical Reviews. 1974. Vol. 43. No. 1. pp. 1-16.
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Labunskaya V. I., Shebaldova A. D., Khidekel' M. L. Catalysis of Symmetry-disallowed Reactions // Russian Chemical Reviews. 1974. Vol. 43. No. 1. pp. 1-16.
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TY - JOUR
DO - 10.1070/RC1974v043n01ABEH001785
UR - https://rcr.colab.ws/publications/10.1070/RC1974v043n01ABEH001785
TI - Catalysis of Symmetry-disallowed Reactions
T2 - Russian Chemical Reviews
AU - Labunskaya, Veronika Iosifovna
AU - Shebaldova, Asya Dmitrievna
AU - Khidekel', Mikhail L'vovich
PY - 1974
DA - 1973/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1-16
IS - 1
VL - 43
ER -
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@article{1974_Labunskaya,
author = {Veronika Iosifovna Labunskaya and Asya Dmitrievna Shebaldova and Mikhail L'vovich Khidekel'},
title = {Catalysis of Symmetry-disallowed Reactions},
journal = {Russian Chemical Reviews},
year = {1974},
volume = {43},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1974v043n01ABEH001785},
number = {1},
pages = {1--16},
doi = {10.1070/RC1974v043n01ABEH001785}
}
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Labunskaya, Veronika Iosifovna, et al. “Catalysis of Symmetry-disallowed Reactions.” Russian Chemical Reviews, vol. 43, no. 1, Nov. 1974, pp. 1-16. https://rcr.colab.ws/publications/10.1070/RC1974v043n01ABEH001785.
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Abstract

Opportunities for applying the principle of the conservation of orbital symmetry to catalytic processes are surveyed. Current views on the role of a transition metal in the catalysis of symmetry-disallowed reactions are reported, and possible mechanisms are discussed. Close attention is paid to the correlation of the catalytic activity of metal-containing catalysts with the electron configuration of the transition metal, the structure of the complex, and the nature of the ligands. Examples of catalytic reactions disallowed by the Woodward–Hoffmann rules – valency isomerisation of hydrocarbons, hydrogenation and disproportionation of alkenes, cyclo-oligomerisation – are considered in the light of ideas on concerted and stepwise mechanisms. A list of 137 references is included.

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