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The Cleavage of the Carbon–Oxygen Bond by Organomagnesium Compounds

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Svetlana Evgenievna Korostova 1
Svetlana Evgenievna Korostova
1 Irkutsk Institute of Chemistry, Siberian Branch of the USSR Academy of Sciences
10.1070/RC1975v044n01ABEH002150
Published 30 November 1974
Communication , Volume 44, Issue 1, 41-55
26
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Trofimov B. A., Korostova S. E. The Cleavage of the Carbon–Oxygen Bond by Organomagnesium Compounds // Russian Chemical Reviews. 1975. Vol. 44. No. 1. pp. 41-55.
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Trofimov B. A., Korostova S. E. The Cleavage of the Carbon–Oxygen Bond by Organomagnesium Compounds // Russian Chemical Reviews. 1975. Vol. 44. No. 1. pp. 41-55.
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TY - JOUR
DO - 10.1070/RC1975v044n01ABEH002150
UR - https://rcr.colab.ws/publications/10.1070/RC1975v044n01ABEH002150
TI - The Cleavage of the Carbon–Oxygen Bond by Organomagnesium Compounds
T2 - Russian Chemical Reviews
AU - Trofimov, Boris Aleksandrovich
AU - Korostova, Svetlana Evgenievna
PY - 1975
DA - 1974/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 41-55
IS - 1
VL - 44
ER -
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@article{1975_Trofimov,
author = {Boris Aleksandrovich Trofimov and Svetlana Evgenievna Korostova},
title = {The Cleavage of the Carbon–Oxygen Bond by Organomagnesium Compounds},
journal = {Russian Chemical Reviews},
year = {1975},
volume = {44},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1975v044n01ABEH002150},
number = {1},
pages = {41--55},
doi = {10.1070/RC1975v044n01ABEH002150}
}
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Trofimov, Boris Aleksandrovich, and Svetlana Evgenievna Korostova. “The Cleavage of the Carbon–Oxygen Bond by Organomagnesium Compounds.” Russian Chemical Reviews, vol. 44, no. 1, Nov. 1975, pp. 41-55. https://rcr.colab.ws/publications/10.1070/RC1975v044n01ABEH002150.
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Abstract

Studies on reactions involving the cleavage of the C–O bond by organomagnesium compounds (OMC) (Grignard and Norman reagents and lotsich complexes), including the behaviour of ethers, open-chain acetals, and cyclic acetals in relation to the OMC, are reviewed. The mechanism of the cleavage of the ether linkage by OMC is discussed, attention being concentrated on the reaction of 1,3-dioxacyclanes with OMC, the complex-formation processes in the reaction of 1,3-dioxolans with Grignard reagents and lotsich complexes, and also the mode of the cleavage of asymmetrically substituted 1,3-dioxacyclanes by these reagents.
The bibliography includes 183 references.