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The Structure and Methods of Synthesis of Thiirans

Alexandr Vasil'evich Fokin 1
Alexandr Vasil'evich Fokin
, 
Aleksei Filippovich Kolomiets 1
Aleksei Filippovich Kolomiets
1 A. N. Nesmeyanov Institute of Organoelement Compounds, USSR Academy of Sciences, Moscow
10.1070/RC1975v044n02ABEH002252
Published 30 November 1974
Communication , Volume 44, Issue 2, 138-153
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Fokin A. V., Kolomiets A. F. The Structure and Methods of Synthesis of Thiirans // Russian Chemical Reviews. 1975. Vol. 44. No. 2. pp. 138-153.
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Fokin A. V., Kolomiets A. F. The Structure and Methods of Synthesis of Thiirans // Russian Chemical Reviews. 1975. Vol. 44. No. 2. pp. 138-153.
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TY - JOUR
DO - 10.1070/RC1975v044n02ABEH002252
UR - https://rcr.colab.ws/publications/10.1070/RC1975v044n02ABEH002252
TI - The Structure and Methods of Synthesis of Thiirans
T2 - Russian Chemical Reviews
AU - Fokin, Alexandr Vasil'evich
AU - Kolomiets, Aleksei Filippovich
PY - 1975
DA - 1974/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 138-153
IS - 2
VL - 44
ER -
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@article{1975_Fokin,
author = {Alexandr Vasil'evich Fokin and Aleksei Filippovich Kolomiets},
title = {The Structure and Methods of Synthesis of Thiirans},
journal = {Russian Chemical Reviews},
year = {1975},
volume = {44},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1975v044n02ABEH002252},
number = {2},
pages = {138--153},
doi = {10.1070/RC1975v044n02ABEH002252}
}
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Fokin, Alexandr Vasil'evich, and Aleksei Filippovich Kolomiets. “The Structure and Methods of Synthesis of Thiirans.” Russian Chemical Reviews, vol. 44, no. 2, Nov. 1975, pp. 138-153. https://rcr.colab.ws/publications/10.1070/RC1975v044n02ABEH002252.
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Abstract

The data presented in the review confirm the earlier results concerning a structural similarity between the two-carbon skeleton of the thiiran ring and the double bond of alkenes.
The available data on the syntheses and structures of thiirans and alkene episulphoxides and episulphones are treated systematically. The methods for the formation of the thiiran ring are classified and synthetic procedures based on homolytic, anionotropic, and cationotropic closure of thiiran rings and on thiiran reactions occurring without the opening of the ring are discussed.
The bibliography includes 236 references.