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Reactivity and Transmission of Electronic Effects in Bridged Bicyclic Systems

Leonid Mikhailovich Litvinenko 1, 2
Leonid Mikhailovich Litvinenko
, 
R S Popova 1, 2
R S Popova
, 
Anatolii Fedorovich Popov 1, 2
Anatolii Fedorovich Popov
1 Donetsk State University
2 Institute of Physical-Organic Chemistry and Coal Chemistry, Academy of Sciences of the Ukrainian SSR, Donetsk
10.1070/RC1975v044n09ABEH002372
Published 30 November 1974
Communication , Volume 44, Issue 9, 718-732
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Litvinenko L. M., Popova R. S., Popov A. F. Reactivity and Transmission of Electronic Effects in Bridged Bicyclic Systems // Russian Chemical Reviews. 1975. Vol. 44. No. 9. pp. 718-732.
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Litvinenko L. M., Popova R. S., Popov A. F. Reactivity and Transmission of Electronic Effects in Bridged Bicyclic Systems // Russian Chemical Reviews. 1975. Vol. 44. No. 9. pp. 718-732.
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TY - JOUR
DO - 10.1070/RC1975v044n09ABEH002372
UR - https://rcr.colab.ws/publications/10.1070/RC1975v044n09ABEH002372
TI - Reactivity and Transmission of Electronic Effects in Bridged Bicyclic Systems
T2 - Russian Chemical Reviews
AU - Litvinenko, Leonid Mikhailovich
AU - Popova, R S
AU - Popov, Anatolii Fedorovich
PY - 1975
DA - 1974/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 718-732
IS - 9
VL - 44
ER -
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@article{1975_Litvinenko,
author = {Leonid Mikhailovich Litvinenko and R S Popova and Anatolii Fedorovich Popov},
title = {Reactivity and Transmission of Electronic Effects in Bridged Bicyclic Systems},
journal = {Russian Chemical Reviews},
year = {1975},
volume = {44},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1975v044n09ABEH002372},
number = {9},
pages = {718--732},
doi = {10.1070/RC1975v044n09ABEH002372}
}
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Litvinenko, Leonid Mikhailovich, et al. “Reactivity and Transmission of Electronic Effects in Bridged Bicyclic Systems.” Russian Chemical Reviews, vol. 44, no. 9, Nov. 1975, pp. 718-732. https://rcr.colab.ws/publications/10.1070/RC1975v044n09ABEH002372.
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Abstract

Analysis of data for the transmission of electronic effects in various biaryl systems has shown that the introduction of a bridge group between two benzene rings can both weaken and enhance the interaction between a substituent and a functional centre located in different rings. The nature and mechanisms of the enhanced transmission of electronic influences in bridged systems, called the positive bridge effect (PBE), have been examined and the principal conditions for the manifestation of PBE have been formulated.
The bibliography includes 192 references.