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Polarographic Study of Aminoalkyl Esters of αβ-Unsaturated Acids and Their Reactions

Yakov Iosifovich Tur'yan 1
Yakov Iosifovich Tur'yan
, 
F K Ignat'eva 1
F K Ignat'eva
, 
M A Korshunov 2
M A Korshunov
, 
Valerii Solomonovich Mikhlin 2
Valerii Solomonovich Mikhlin
1 Krasnodar Technical Institute
2 Research Institute "Yarsintez", Yaroslavl'
10.1070/RC1976v045n02ABEH002611
Published 30 November 1975
Communication , Volume 45, Issue 2, 111-126
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Tur'yan Y. I. et al. Polarographic Study of Aminoalkyl Esters of αβ-Unsaturated Acids and Their Reactions // Russian Chemical Reviews. 1976. Vol. 45. No. 2. pp. 111-126.
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Tur'yan Y. I., Ignat'eva F. K., Korshunov M. A., Mikhlin V. S. Polarographic Study of Aminoalkyl Esters of αβ-Unsaturated Acids and Their Reactions // Russian Chemical Reviews. 1976. Vol. 45. No. 2. pp. 111-126.
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TY - JOUR
DO - 10.1070/RC1976v045n02ABEH002611
UR - https://rcr.colab.ws/publications/10.1070/RC1976v045n02ABEH002611
TI - Polarographic Study of Aminoalkyl Esters of αβ-Unsaturated Acids and Their Reactions
T2 - Russian Chemical Reviews
AU - Tur'yan, Yakov Iosifovich
AU - Ignat'eva, F K
AU - Korshunov, M A
AU - Mikhlin, Valerii Solomonovich
PY - 1976
DA - 1975/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 111-126
IS - 2
VL - 45
ER -
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@article{1976_Tur'yan,
author = {Yakov Iosifovich Tur'yan and F K Ignat'eva and M A Korshunov and Valerii Solomonovich Mikhlin},
title = {Polarographic Study of Aminoalkyl Esters of αβ-Unsaturated Acids and Their Reactions},
journal = {Russian Chemical Reviews},
year = {1976},
volume = {45},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1976v045n02ABEH002611},
number = {2},
pages = {111--126},
doi = {10.1070/RC1976v045n02ABEH002611}
}
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Tur'yan, Yakov Iosifovich, et al. “Polarographic Study of Aminoalkyl Esters of αβ-Unsaturated Acids and Their Reactions.” Russian Chemical Reviews, vol. 45, no. 2, Nov. 1976, pp. 111-126. https://rcr.colab.ws/publications/10.1070/RC1976v045n02ABEH002611.
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Abstract

The review is devoted to the polarographic study of the reactions of aminoalkyl esters of αβ-unsaturated acids: electrochemical reduction, hydrolysis (including hydrolysis in a two-phase system), partition, and isomerisation. Detailed polarographic characteristics and equations for the polarographic wave and the kinetics and equilibria of the reactions using the limiting polarographic current are presented. The corresponding analytical applications of the method are considered. The kinetics and mechanisms of the processes are discussed from the standpoint of the structure of the electrical double layer, the acid–base properties of the aminoalkyl esters, and intramolecular hydrogen bonds in conjunction with correlation analysis. A comparison is made with data obtained by pH-stat and spectrophotometric methods.
The bibliography includes 166 references.