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Hydrogenation of Alkenes on Oxide Catalysts

Khabib Minachevich Minachev 1
Khabib Minachevich Minachev
, 
Yurii Stepanovich Khodakov 1
Yurii Stepanovich Khodakov
, 
Vyacheslav Safan'evich Nakhshunov 1
Vyacheslav Safan'evich Nakhshunov
1 N. D. Zelinskii Institute of Organic Chemistry of the USSR Academy of Sciences, Moscow
Published 30 November 1975
Communication , Volume 45, Issue 2, 142-154
6
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Minachev K. M., Khodakov Y. S., Nakhshunov V. S. Hydrogenation of Alkenes on Oxide Catalysts // Russian Chemical Reviews. 1976. Vol. 45. No. 2. pp. 142-154.
GOST all authors (up to 50)
Minachev K. M., Khodakov Y. S., Nakhshunov V. S. Hydrogenation of Alkenes on Oxide Catalysts // Russian Chemical Reviews. 1976. Vol. 45. No. 2. pp. 142-154.
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TY - JOUR
DO - 10.1070/RC1976v045n02ABEH002616
UR - https://rcr.colab.ws/publications/10.1070/RC1976v045n02ABEH002616
TI - Hydrogenation of Alkenes on Oxide Catalysts
T2 - Russian Chemical Reviews
AU - Minachev, Khabib Minachevich
AU - Khodakov, Yurii Stepanovich
AU - Nakhshunov, Vyacheslav Safan'evich
PY - 1976
DA - 1975/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 142-154
IS - 2
VL - 45
ER -
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@article{1976_Minachev,
author = {Khabib Minachevich Minachev and Yurii Stepanovich Khodakov and Vyacheslav Safan'evich Nakhshunov},
title = {Hydrogenation of Alkenes on Oxide Catalysts},
journal = {Russian Chemical Reviews},
year = {1976},
volume = {45},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1976v045n02ABEH002616},
number = {2},
pages = {142--154},
doi = {10.1070/RC1976v045n02ABEH002616}
}
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Minachev, Khabib Minachevich, et al. “Hydrogenation of Alkenes on Oxide Catalysts.” Russian Chemical Reviews, vol. 45, no. 2, Nov. 1976, pp. 142-154. https://rcr.colab.ws/publications/10.1070/RC1976v045n02ABEH002616.
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Abstract

A qualitative survey of available data has enabled pure oxides to be divided into five groups according to their catalytic activity. Zeolites are less active than oxides corresponding to their cationic forms. The activity of an oxide catalyst either increases continuously or passes through a maximum with increase in its temperature of ignition. This type of dependence is explained by the surface dehydroxylation model on the assumption that the activity is determined by the presence of electron-donating and electron-accepting sites situated side by side on the surface. The hydrogenation of alkenes involves stages of activation of the alkene and of hydrogen, with on most oxides appearance of a semi-hydrogenated form.
A list of 91 references is included.