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Some Aspects of the Theory of Gel Formation in Reactions of Polyfunctional Compounds

Kuz'ma Andrianovich Andrianov 1
Kuz'ma Andrianovich Andrianov
, 
V N Emel'yanov 1
V N Emel'yanov
1 A. N. Nesmeyanov Institute of Organoelement Compounds, USSR Academy of Sciences, Moscow
10.1070/RC1976v045n10ABEH002742
Published 30 November 1975
Communication , Volume 45, Issue 10, 931-945
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Andrianov K. A., Emel'yanov V. N. Some Aspects of the Theory of Gel Formation in Reactions of Polyfunctional Compounds // Russian Chemical Reviews. 1976. Vol. 45. No. 10. pp. 931-945.
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Andrianov K. A., Emel'yanov V. N. Some Aspects of the Theory of Gel Formation in Reactions of Polyfunctional Compounds // Russian Chemical Reviews. 1976. Vol. 45. No. 10. pp. 931-945.
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TY - JOUR
DO - 10.1070/RC1976v045n10ABEH002742
UR - https://rcr.colab.ws/publications/10.1070/RC1976v045n10ABEH002742
TI - Some Aspects of the Theory of Gel Formation in Reactions of Polyfunctional Compounds
T2 - Russian Chemical Reviews
AU - Andrianov, Kuz'ma Andrianovich
AU - Emel'yanov, V N
PY - 1976
DA - 1975/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 931-945
IS - 10
VL - 45
ER -
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@article{1976_Andrianov,
author = {Kuz'ma Andrianovich Andrianov and V N Emel'yanov},
title = {Some Aspects of the Theory of Gel Formation in Reactions of Polyfunctional Compounds},
journal = {Russian Chemical Reviews},
year = {1976},
volume = {45},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1976v045n10ABEH002742},
number = {10},
pages = {931--945},
doi = {10.1070/RC1976v045n10ABEH002742}
}
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Andrianov, Kuz'ma Andrianovich, and V N Emel'yanov. “Some Aspects of the Theory of Gel Formation in Reactions of Polyfunctional Compounds.” Russian Chemical Reviews, vol. 45, no. 10, Nov. 1976, pp. 931-945. https://rcr.colab.ws/publications/10.1070/RC1976v045n10ABEH002742.
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Abstract

Various theories of gel formation by three-dimensional polymers derived from polyfunctional monomeric and oligomeric compounds, ranging from the theory of Carothers and Flory to the modern theories of Gordon, Kilb, Frisch, Bruneau, and Stepto, are discussed. The role of kinetic, thermodynamic, and structural factors in processes leading to the development of the gel fraction are analysed. The reactions involving polyfunctional compounds are classified, and the fundamental scheme of the three-dimensional reaction leading to gel polymers is described taking into account the altered ideas and the new criteria which have been established. The conclusions reached at a symposium on gel formation processes in polymers held in England in 1974 are examined.
The bibliography includes 149 references.

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