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Theory of Complex Unimolecular Reactions

Aleksandr Davidovich Berman 1
Aleksandr Davidovich Berman
1 Institute of Chemical Physics of the USSR Academy of Sciences, Moscow
Published 30 November 1975
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Berman A. D. Theory of Complex Unimolecular Reactions // Russian Chemical Reviews. 1976. Vol. 45. No. 11. pp. 983-1007.
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Berman A. D. Theory of Complex Unimolecular Reactions // Russian Chemical Reviews. 1976. Vol. 45. No. 11. pp. 983-1007.
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TY - JOUR
DO - 10.1070/RC1976v045n11ABEH002748
UR - https://rcr.colab.ws/publications/10.1070/RC1976v045n11ABEH002748
TI - Theory of Complex Unimolecular Reactions
T2 - Russian Chemical Reviews
AU - Berman, Aleksandr Davidovich
PY - 1976
DA - 1975/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 983-1007
IS - 11
VL - 45
ER -
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@article{1976_Berman,
author = {Aleksandr Davidovich Berman},
title = {Theory of Complex Unimolecular Reactions},
journal = {Russian Chemical Reviews},
year = {1976},
volume = {45},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1976v045n11ABEH002748},
number = {11},
pages = {983--1007},
doi = {10.1070/RC1976v045n11ABEH002748}
}
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Berman, Aleksandr Davidovich. “Theory of Complex Unimolecular Reactions.” Russian Chemical Reviews, vol. 45, no. 11, Nov. 1976, pp. 983-1007. https://rcr.colab.ws/publications/10.1070/RC1976v045n11ABEH002748.
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Abstract

A general approach to the study of complex reacting systems, including first-order reactions, is considered. The method consists in the identification of the disposition of the characteristic vectors of the kinetic matrix for a linear system and their eigenvalues. Linear reaction pathways in the composition space correspond to non-equilibrium characteristic vectors. For an experimental determination of the kinetic constants in a complex system, it is sufficient to find all the linear reaction pathways.
The bibliography includes 56 references.