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Rearrangements in Sulphoxides and Sulphones Induced by Electron Impact

Ryurik Arkad'evich Khmel'nitskii 1
Ryurik Arkad'evich Khmel'nitskii
, 
Yurii Aleksandrovich Efremov 1
Yurii Aleksandrovich Efremov
1 Moscow Timiryazev Agricultural Academy
10.1070/RC1977v046n01ABEH002119
Published 30 November 1976
Communication , Volume 46, Issue 1, 46-58
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Khmel'nitskii R. A., Efremov Y. A. Rearrangements in Sulphoxides and Sulphones Induced by Electron Impact // Russian Chemical Reviews. 1977. Vol. 46. No. 1. pp. 46-58.
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Khmel'nitskii R. A., Efremov Y. A. Rearrangements in Sulphoxides and Sulphones Induced by Electron Impact // Russian Chemical Reviews. 1977. Vol. 46. No. 1. pp. 46-58.
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TY - JOUR
DO - 10.1070/RC1977v046n01ABEH002119
UR - https://rcr.colab.ws/publications/10.1070/RC1977v046n01ABEH002119
TI - Rearrangements in Sulphoxides and Sulphones Induced by Electron Impact
T2 - Russian Chemical Reviews
AU - Khmel'nitskii, Ryurik Arkad'evich
AU - Efremov, Yurii Aleksandrovich
PY - 1977
DA - 1976/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 46-58
IS - 1
VL - 46
ER -
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@article{1977_Khmel'nitskii,
author = {Ryurik Arkad'evich Khmel'nitskii and Yurii Aleksandrovich Efremov},
title = {Rearrangements in Sulphoxides and Sulphones Induced by Electron Impact},
journal = {Russian Chemical Reviews},
year = {1977},
volume = {46},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1977v046n01ABEH002119},
number = {1},
pages = {46--58},
doi = {10.1070/RC1977v046n01ABEH002119}
}
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Khmel'nitskii, Ryurik Arkad'evich, and Yurii Aleksandrovich Efremov. “Rearrangements in Sulphoxides and Sulphones Induced by Electron Impact.” Russian Chemical Reviews, vol. 46, no. 1, Nov. 1977, pp. 46-58. https://rcr.colab.ws/publications/10.1070/RC1977v046n01ABEH002119.
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Abstract

The survey covers processes involving the isomerisation of molecular ions and the rearrangement of ionic fragments during the initial stages of the dissociative ionisation of sulphoxides and sulphones on electron bombardment. Characteristic ions are formed by skeletal rearrangements, in particular by migration of an alkyl or an aryl group from the sulphur to an oxygen atom. The relative statistical weight of a particular structure of a molecular ion is the main factor determining subsequent competitive decomposition paths of the primary ionic fragments. A list of 82 references is included.