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Tertiary Amines in Acyl Transfer Reactions

E M Cherkasova 1
E M Cherkasova
, 
Stanislav Vsevolodovich Bogatkov 1
Stanislav Vsevolodovich Bogatkov
, 
Zinaida Pavlovna Golovina 1
Zinaida Pavlovna Golovina
1 M. V. Lomonosov Moscow Institute of Fine Chemical Technology
10.1070/RC1977v046n03ABEH002130
Published 30 November 1976
Communication , Volume 46, Issue 3, 246-263
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Cherkasova E. M., Bogatkov S. V., Golovina Z. P. Tertiary Amines in Acyl Transfer Reactions // Russian Chemical Reviews. 1977. Vol. 46. No. 3. pp. 246-263.
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Cherkasova E. M., Bogatkov S. V., Golovina Z. P. Tertiary Amines in Acyl Transfer Reactions // Russian Chemical Reviews. 1977. Vol. 46. No. 3. pp. 246-263.
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TY - JOUR
DO - 10.1070/RC1977v046n03ABEH002130
UR - https://rcr.colab.ws/publications/10.1070/RC1977v046n03ABEH002130
TI - Tertiary Amines in Acyl Transfer Reactions
T2 - Russian Chemical Reviews
AU - Cherkasova, E M
AU - Bogatkov, Stanislav Vsevolodovich
AU - Golovina, Zinaida Pavlovna
PY - 1977
DA - 1976/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 246-263
IS - 3
VL - 46
ER -
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@article{1977_Cherkasova,
author = {E M Cherkasova and Stanislav Vsevolodovich Bogatkov and Zinaida Pavlovna Golovina},
title = {Tertiary Amines in Acyl Transfer Reactions},
journal = {Russian Chemical Reviews},
year = {1977},
volume = {46},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1977v046n03ABEH002130},
number = {3},
pages = {246--263},
doi = {10.1070/RC1977v046n03ABEH002130}
}
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Cherkasova, E. M., et al. “Tertiary Amines in Acyl Transfer Reactions.” Russian Chemical Reviews, vol. 46, no. 3, Nov. 1977, pp. 246-263. https://rcr.colab.ws/publications/10.1070/RC1977v046n03ABEH002130.
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Abstract

The mechanism and kinetics of acyl transfer reactions in the presence of tertiary amines are examined and the quantitative relations between the rate of reaction and the structure of the acylating agent, the acylated substrate, the amine, and the solvent, temperature, and the ratio of the efficiencies of intramolecular and intermolecular catalysis are discussed. A number of examples of the application of tertiary amines as accelerators of acyl transfer reactions, which are of practical importance, are presented.
The bibliography includes 282 references.