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The Chemistry of the Surfaces of the Acid Forms of Natural Layer Silicates

Nikolai Grigor'evich Vasil'ev 1
Nikolai Grigor'evich Vasil'ev
, 
Fedor Danilovich Ovcharenko 1
Fedor Danilovich Ovcharenko
1 Institute of Colloid Chemistry and Chemistry of Water, Academy of Sciences of the Ukrainian SSR, Kiev
10.1070/RC1977v046n08ABEH002172
Published 30 November 1976
Communication , Volume 46, Issue 8, 775-788
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Vasil'ev N. G., Ovcharenko F. D. The Chemistry of the Surfaces of the Acid Forms of Natural Layer Silicates // Russian Chemical Reviews. 1977. Vol. 46. No. 8. pp. 775-788.
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Vasil'ev N. G., Ovcharenko F. D. The Chemistry of the Surfaces of the Acid Forms of Natural Layer Silicates // Russian Chemical Reviews. 1977. Vol. 46. No. 8. pp. 775-788.
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TY - JOUR
DO - 10.1070/RC1977v046n08ABEH002172
UR - https://rcr.colab.ws/publications/10.1070/RC1977v046n08ABEH002172
TI - The Chemistry of the Surfaces of the Acid Forms of Natural Layer Silicates
T2 - Russian Chemical Reviews
AU - Vasil'ev, Nikolai Grigor'evich
AU - Ovcharenko, Fedor Danilovich
PY - 1977
DA - 1976/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 775-788
IS - 8
VL - 46
ER -
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@article{1977_Vasil'ev,
author = {Nikolai Grigor'evich Vasil'ev and Fedor Danilovich Ovcharenko},
title = {The Chemistry of the Surfaces of the Acid Forms of Natural Layer Silicates},
journal = {Russian Chemical Reviews},
year = {1977},
volume = {46},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1977v046n08ABEH002172},
number = {8},
pages = {775--788},
doi = {10.1070/RC1977v046n08ABEH002172}
}
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Vasil'ev, Nikolai Grigor'evich, and Fedor Danilovich Ovcharenko. “The Chemistry of the Surfaces of the Acid Forms of Natural Layer Silicates.” Russian Chemical Reviews, vol. 46, no. 8, Nov. 1977, pp. 775-788. https://rcr.colab.ws/publications/10.1070/RC1977v046n08ABEH002172.
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Abstract

Modern ideas about the nature of the exchangeable acidity of a group of layer silicates (clay minerals) are described and the results obtained during the last decade with the aid of physical and physicochemical techniques are surveyed. The dependence of the surface acidity on non-stoichiometric substitutions in the structure of the minerals, the influence of a number of factors on the spontaneous conversion of the H-forms of the silicates into AI-Fe-Mg-forms, the mechanism of this phenomenon, the ion-exchange properties and the thermal stabilities of the H- and AI-Fe-Mg-forms, and other problems are examined.
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