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Arynes and Carbenes Derived from Organoelement Compounds

Oleg Matveevich Nefedov 1
Oleg Matveevich Nefedov
, 
A I D'yachenko 1
A I D'yachenko
, 
A K Prokof'ev 2
A K Prokof'ev
1 N. D. Zelinskii Institute of Organic Chemistry of the USSR Academy of Sciences, Moscow
2 State Institute of Oceanography, Moscow
10.1070/RC1977v046n10ABEH002184
Published 30 November 1976
Communication , Volume 46, Issue 10, 941-966
29
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Nefedov O. M., D'yachenko A. I., Prokof'ev A. K. Arynes and Carbenes Derived from Organoelement Compounds // Russian Chemical Reviews. 1977. Vol. 46. No. 10. pp. 941-966.
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Nefedov O. M., D'yachenko A. I., Prokof'ev A. K. Arynes and Carbenes Derived from Organoelement Compounds // Russian Chemical Reviews. 1977. Vol. 46. No. 10. pp. 941-966.
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TY - JOUR
DO - 10.1070/RC1977v046n10ABEH002184
UR - https://rcr.colab.ws/publications/10.1070/RC1977v046n10ABEH002184
TI - Arynes and Carbenes Derived from Organoelement Compounds
T2 - Russian Chemical Reviews
AU - Nefedov, Oleg Matveevich
AU - D'yachenko, A I
AU - Prokof'ev, A K
PY - 1977
DA - 1976/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 941-966
IS - 10
VL - 46
ER -
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@article{1977_Nefedov,
author = {Oleg Matveevich Nefedov and A I D'yachenko and A K Prokof'ev},
title = {Arynes and Carbenes Derived from Organoelement Compounds},
journal = {Russian Chemical Reviews},
year = {1977},
volume = {46},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1977v046n10ABEH002184},
number = {10},
pages = {941--966},
doi = {10.1070/RC1977v046n10ABEH002184}
}
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Nefedov, Oleg Matveevich, et al. “Arynes and Carbenes Derived from Organoelement Compounds.” Russian Chemical Reviews, vol. 46, no. 10, Nov. 1977, pp. 941-966. https://rcr.colab.ws/publications/10.1070/RC1977v046n10ABEH002184.
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Abstract

The literature data on the methods for the synthesis of unstable intermediate species (arynes and carbenes) from organoelement compounds, mainly from o- and α-halogeno-derivatives, are surveyed and examined critically. It is shown that the ease of decomposition of the initial compound is determined by the possibility of the formation in the transition state of the coordinate bond between the groups or atoms eliminated and the theoretical proof of this mechanism is given.
The bibliography includes 322 references.