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Recent Equilibrium and Kinetic Studies of the Adsorption of Gases and Vapours by Microporous Adsorbents

Mikhail Mikhailovich Dubinin 1
Mikhail Mikhailovich Dubinin
1 Institute of Physical Chemistry, the USSR Academy of Sciences, Moscow
10.1070/RC1977v046n11ABEH002188
Published 30 November 1976
Communication , Volume 46, Issue 11, 1021-1029
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Dubinin M. M. Recent Equilibrium and Kinetic Studies of the Adsorption of Gases and Vapours by Microporous Adsorbents // Russian Chemical Reviews. 1977. Vol. 46. No. 11. pp. 1021-1029.
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Dubinin M. M. Recent Equilibrium and Kinetic Studies of the Adsorption of Gases and Vapours by Microporous Adsorbents // Russian Chemical Reviews. 1977. Vol. 46. No. 11. pp. 1021-1029.
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TY - JOUR
DO - 10.1070/RC1977v046n11ABEH002188
UR - https://rcr.colab.ws/publications/10.1070/RC1977v046n11ABEH002188
TI - Recent Equilibrium and Kinetic Studies of the Adsorption of Gases and Vapours by Microporous Adsorbents
T2 - Russian Chemical Reviews
AU - Dubinin, Mikhail Mikhailovich
PY - 1977
DA - 1976/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1021-1029
IS - 11
VL - 46
ER -
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@article{1977_Dubinin,
author = {Mikhail Mikhailovich Dubinin},
title = {Recent Equilibrium and Kinetic Studies of the Adsorption of Gases and Vapours by Microporous Adsorbents},
journal = {Russian Chemical Reviews},
year = {1977},
volume = {46},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1977v046n11ABEH002188},
number = {11},
pages = {1021--1029},
doi = {10.1070/RC1977v046n11ABEH002188}
}
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Dubinin, Mikhail Mikhailovich. “Recent Equilibrium and Kinetic Studies of the Adsorption of Gases and Vapours by Microporous Adsorbents.” Russian Chemical Reviews, vol. 46, no. 11, Nov. 1977, pp. 1021-1029. https://rcr.colab.ws/publications/10.1070/RC1977v046n11ABEH002188.
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Abstract

Thermodynamic theories of adsorption equilibrium in micropores are discussed with special reference to the osmotic theory of adsorption, based on the vacancy solution model, and to the analogy between adsorption and osmotic equilibria. A thermal adsorption equation is derived, and its special cases are discussed, thus giving a quantitative description of adsorption on microporous adsorbents over a wide range of pressure and temperature. New methods of investigating the kinetics of vapour adsorption on microporous adsorbents and of describing the process theoretically by the bipore model are reviewed. Good agreement between experiment and theory is obtained. 40 references.