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Advances in the Chemistry of Ambident Enolate and Phenoxide Ions

Oleg Aleksandrovich Reutov 1
Oleg Aleksandrovich Reutov
, 
Aleksandr Leonidovich Kurts 1
Aleksandr Leonidovich Kurts
1 Lomonosov Moscow State University, Faculty of Chemistry
10.1070/RC1977v046n11ABEH002190
Published 30 November 1976
Communication , Volume 46, Issue 11, 1040-1056
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Reutov O. A., Kurts A. L. Advances in the Chemistry of Ambident Enolate and Phenoxide Ions // Russian Chemical Reviews. 1977. Vol. 46. No. 11. pp. 1040-1056.
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Reutov O. A., Kurts A. L. Advances in the Chemistry of Ambident Enolate and Phenoxide Ions // Russian Chemical Reviews. 1977. Vol. 46. No. 11. pp. 1040-1056.
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TY - JOUR
DO - 10.1070/RC1977v046n11ABEH002190
UR - https://rcr.colab.ws/publications/10.1070/RC1977v046n11ABEH002190
TI - Advances in the Chemistry of Ambident Enolate and Phenoxide Ions
T2 - Russian Chemical Reviews
AU - Reutov, Oleg Aleksandrovich
AU - Kurts, Aleksandr Leonidovich
PY - 1977
DA - 1976/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1040-1056
IS - 11
VL - 46
ER -
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@article{1977_Reutov,
author = {Oleg Aleksandrovich Reutov and Aleksandr Leonidovich Kurts},
title = {Advances in the Chemistry of Ambident Enolate and Phenoxide Ions},
journal = {Russian Chemical Reviews},
year = {1977},
volume = {46},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1977v046n11ABEH002190},
number = {11},
pages = {1040--1056},
doi = {10.1070/RC1977v046n11ABEH002190}
}
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Reutov, Oleg Aleksandrovich, and Aleksandr Leonidovich Kurts. “Advances in the Chemistry of Ambident Enolate and Phenoxide Ions.” Russian Chemical Reviews, vol. 46, no. 11, Nov. 1977, pp. 1040-1056. https://rcr.colab.ws/publications/10.1070/RC1977v046n11ABEH002190.
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Abstract

The reactivities of ambident enolate and phenoxide ions in alkylation reactions are examined. It is shown that the mode of C- and O-alkylation of an ambident anion is determined by the structures of the alkyl group and the group eliminated from the alkylating agent, the nature of the solvent, and the type of counter ion. The influence of each of these factors on the dual reactivity of the enolates of carbonyl and β-dicarbonyl compounds and esters as well as phenoxides and naphthoxides is analysed in detail.
The bibliography includes 160 references.