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Reactions of Carbanions and Halogenocarbenes in Two-phase Systems

1 Institute of Organic Chemistry PAS, Poland
10.1070/RC1977v046n12ABEH002196
Published 30 November 1976
Communication , Volume 46, Issue 12, 1151-1166
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Makosza M. Reactions of Carbanions and Halogenocarbenes in Two-phase Systems // Russian Chemical Reviews. 1977. Vol. 46. No. 12. pp. 1151-1166.
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Makosza M. Reactions of Carbanions and Halogenocarbenes in Two-phase Systems // Russian Chemical Reviews. 1977. Vol. 46. No. 12. pp. 1151-1166.
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TY - JOUR
DO - 10.1070/RC1977v046n12ABEH002196
UR - https://rcr.colab.ws/publications/10.1070/RC1977v046n12ABEH002196
TI - Reactions of Carbanions and Halogenocarbenes in Two-phase Systems
T2 - Russian Chemical Reviews
AU - Makosza, Mieczyslaw
PY - 1977
DA - 1976/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1151-1166
IS - 12
VL - 46
ER -
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@article{1977_Makosza,
author = {Mieczyslaw Makosza},
title = {Reactions of Carbanions and Halogenocarbenes in Two-phase Systems},
journal = {Russian Chemical Reviews},
year = {1977},
volume = {46},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1977v046n12ABEH002196},
number = {12},
pages = {1151--1166},
doi = {10.1070/RC1977v046n12ABEH002196}
}
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Makosza, Mieczyslaw. “Reactions of Carbanions and Halogenocarbenes in Two-phase Systems.” Russian Chemical Reviews, vol. 46, no. 12, Nov. 1977, pp. 1151-1166. https://rcr.colab.ws/publications/10.1070/RC1977v046n12ABEH002196.
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Abstract

The review surveys studies on a new two-phase catalytic method whereby reactions between carbanions and halogenocarbenes can be carried out. Numerous examples of the successful application of this method to various (mainly alkylation) reactions of carbanions and halogenocarbenes are given and the advantages, disadvantages, and limitations of the method compared with the traditional single-phase or pseudo-single-phase methods are discussed. Possible mechanisms of catalysis by ammonium salts in these systems are also considered.
The bibliography includes 261 references.