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Organic Peroxides of Alkali Metals (Alkali Salts of Hydroperoxides)

N A Sokolov 1
N A Sokolov
, 
Yurii Arsent'evich Aleksandrov 1
Yurii Arsent'evich Aleksandrov
1 Chemistry Research Institute of N. I. Lobachevsky, State University of Gor'kii
10.1070/RC1978v047n02ABEH002210
Published 30 November 1977
Communication , Volume 47, Issue 2, 172-185
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Sokolov N. A., Aleksandrov Y. A. Organic Peroxides of Alkali Metals (Alkali Salts of Hydroperoxides) // Russian Chemical Reviews. 1978. Vol. 47. No. 2. pp. 172-185.
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Sokolov N. A., Aleksandrov Y. A. Organic Peroxides of Alkali Metals (Alkali Salts of Hydroperoxides) // Russian Chemical Reviews. 1978. Vol. 47. No. 2. pp. 172-185.
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TY - JOUR
DO - 10.1070/RC1978v047n02ABEH002210
UR - https://rcr.colab.ws/publications/10.1070/RC1978v047n02ABEH002210
TI - Organic Peroxides of Alkali Metals (Alkali Salts of Hydroperoxides)
T2 - Russian Chemical Reviews
AU - Sokolov, N A
AU - Aleksandrov, Yurii Arsent'evich
PY - 1978
DA - 1977/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 172-185
IS - 2
VL - 47
ER -
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@article{1978_Sokolov,
author = {N A Sokolov and Yurii Arsent'evich Aleksandrov},
title = {Organic Peroxides of Alkali Metals (Alkali Salts of Hydroperoxides)},
journal = {Russian Chemical Reviews},
year = {1978},
volume = {47},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1978v047n02ABEH002210},
number = {2},
pages = {172--185},
doi = {10.1070/RC1978v047n02ABEH002210}
}
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Sokolov, N. A., and Yurii Arsent'evich Aleksandrov. “Organic Peroxides of Alkali Metals (Alkali Salts of Hydroperoxides).” Russian Chemical Reviews, vol. 47, no. 2, Nov. 1978, pp. 172-185. https://rcr.colab.ws/publications/10.1070/RC1978v047n02ABEH002210.
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Abstract

Methods of making non-solvated lithium, sodium, and potassium salts of hydroperoxides in hydrocarbon media are considered. Results on the kinetics and mechanism of thermal decomposition of alkali organic peroxides and the reactions of these compounds with alcohols, aldehydes, ketones, esters, and nitriles are discussed. The role of complex formation by the alkali salts of hydroperoxides with donors of protons and Lewis bases is considered. Methods of making organic and organoelemental peroxides based on salts of the hydroperoxides are discussed. 167 references.