Home / Articles / The Hydroperoxy-radical ($\mathrm{H}\dot{\mathrm{O}}_2$) in V.~V.~Voevodskii's Research and at the Present Time. Results and Problems

The Hydroperoxy-radical ($\mathrm{H}\dot{\mathrm{O}}_2$) in V.~V.~Voevodskii's Research and at the Present Time. Results and Problems

Viktor L'vovich Tal'roze 1
Viktor L'vovich Tal'roze
, 
Ariadna Ivanovna Poroikova 1
Ariadna Ivanovna Poroikova
1 Institute of Chemical Physics of the USSR Academy of Sciences, Moscow
10.1070/RC1978v047n06ABEH002234
Published 30 November 1977
Communication , Volume 47, Issue 6, 496-502
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Tal'roze V. L., Poroikova A. I. The Hydroperoxy-radical ($\mathrm{H}\dot{\mathrm{O}}_2$) in V.~V.~Voevodskii's Research and at the Present Time. Results and Problems // Russian Chemical Reviews. 1978. Vol. 47. No. 6. pp. 496-502.
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Tal'roze V. L., Poroikova A. I. The Hydroperoxy-radical ($\mathrm{H}\dot{\mathrm{O}}_2$) in V.~V.~Voevodskii's Research and at the Present Time. Results and Problems // Russian Chemical Reviews. 1978. Vol. 47. No. 6. pp. 496-502.
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TY - JOUR
DO - 10.1070/RC1978v047n06ABEH002234
UR - https://rcr.colab.ws/publications/10.1070/RC1978v047n06ABEH002234
TI - The Hydroperoxy-radical ($\mathrm{H}\dot{\mathrm{O}}_2$) in V.~V.~Voevodskii's Research and at the Present Time. Results and Problems
T2 - Russian Chemical Reviews
AU - Tal'roze, Viktor L'vovich
AU - Poroikova, Ariadna Ivanovna
PY - 1978
DA - 1977/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 496-502
IS - 6
VL - 47
ER -
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@article{1978_Tal'roze,
author = {Viktor L'vovich Tal'roze and Ariadna Ivanovna Poroikova},
title = {The Hydroperoxy-radical ($\mathrm{H}\dot{\mathrm{O}}_2$) in V.~V.~Voevodskii's Research and at the Present Time. Results and Problems},
journal = {Russian Chemical Reviews},
year = {1978},
volume = {47},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1978v047n06ABEH002234},
number = {6},
pages = {496--502},
doi = {10.1070/RC1978v047n06ABEH002234}
}
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Tal'roze, Viktor L'vovich, and Ariadna Ivanovna Poroikova. “The Hydroperoxy-radical ($\mathrm{H}\dot{\mathrm{O}}_2$) in V.~V.~Voevodskii's Research and at the Present Time. Results and Problems.” Russian Chemical Reviews, vol. 47, no. 6, Nov. 1978, pp. 496-502. https://rcr.colab.ws/publications/10.1070/RC1978v047n06ABEH002234.
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Abstract

The role of $\mathrm{H}\dot{\mathrm{O}}_2$ radicals in the kinetics of the gas-phase oxidation of hydrogen-containing substances is considered. It is shown that at a high concentration of active centres, for example, when the latter are generated under the influence of a fairly powerful radiation source, non-linear reactions of $\mathrm{H}\dot{\mathrm{O}}_2$ radicals, i.e. their interaction with one another and with other active species, become important. These processes play an important role in the following kinetic systems considered: at the second limit in mixtures of hydrogen with oxygen under the conditions of artificial chain initiation; in the region of Earth's ozone layer; in lasers based on the reactions between $\mathrm{H}_2$ and $\mathrm{F}_2$.

The bibliography includes 44 references.