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Radical Pairs in the Study of Elementary Chemical Reactions in Solid Organic Substances

Ol'ga Evgen'evna Yakimchenko 1
Ol'ga Evgen'evna Yakimchenko
, 
Yakov Sergeevich Lebedev 1
Yakov Sergeevich Lebedev
1 Institute of Chemical Physics of the USSR Academy of Sciences, Moscow
10.1070/RC1978v047n06ABEH002237
Published 30 November 1977
Communication , Volume 47, Issue 6, 531-548
15
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Yakimchenko O. E., Lebedev Y. S. Radical Pairs in the Study of Elementary Chemical Reactions in Solid Organic Substances // Russian Chemical Reviews. 1978. Vol. 47. No. 6. pp. 531-548.
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Yakimchenko O. E., Lebedev Y. S. Radical Pairs in the Study of Elementary Chemical Reactions in Solid Organic Substances // Russian Chemical Reviews. 1978. Vol. 47. No. 6. pp. 531-548.
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TY - JOUR
DO - 10.1070/RC1978v047n06ABEH002237
UR - https://rcr.colab.ws/publications/10.1070/RC1978v047n06ABEH002237
TI - Radical Pairs in the Study of Elementary Chemical Reactions in Solid Organic Substances
T2 - Russian Chemical Reviews
AU - Yakimchenko, Ol'ga Evgen'evna
AU - Lebedev, Yakov Sergeevich
PY - 1978
DA - 1977/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 531-548
IS - 6
VL - 47
ER -
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@article{1978_Yakimchenko,
author = {Ol'ga Evgen'evna Yakimchenko and Yakov Sergeevich Lebedev},
title = {Radical Pairs in the Study of Elementary Chemical Reactions in Solid Organic Substances},
journal = {Russian Chemical Reviews},
year = {1978},
volume = {47},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1978v047n06ABEH002237},
number = {6},
pages = {531--548},
doi = {10.1070/RC1978v047n06ABEH002237}
}
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Yakimchenko, Ol'ga Evgen'evna, and Yakov Sergeevich Lebedev. “Radical Pairs in the Study of Elementary Chemical Reactions in Solid Organic Substances.” Russian Chemical Reviews, vol. 47, no. 6, Nov. 1978, pp. 531-548. https://rcr.colab.ws/publications/10.1070/RC1978v047n06ABEH002237.
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Abstract

Methods for the investigation of elementary chemical reactions and molecular motions on the basis of the EPR spectra of radical pairs are examined. The results of the study of the stereochemistry and kinetics of processes involving radical pairs are used to discuss the nature of the characteristic features of the elementary solid-phase reactions: the existence of a broad spectrum of the frequencies of the reactions and molecular motions, the reaction mechanisms at low temperatures, and the influence of intra- and inter-molecular motions on the rates of chemical reactions.
The bibliography includes 92 references.