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Solid-phase Radical Reactions and Mechanism of Oxidation of Carbon-chain Polymers

Evgenii Timofeevich Denisov 1
Evgenii Timofeevich Denisov
1 Chernogolovka Institute of Chemical Physics of the USSR Academy of Sciences
Published 30 November 1977
Communication , Volume 47, Issue 6, 572-586
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Denisov E. T. Solid-phase Radical Reactions and Mechanism of Oxidation of Carbon-chain Polymers // Russian Chemical Reviews. 1978. Vol. 47. No. 6. pp. 572-586.
GOST all authors (up to 50)
Denisov E. T. Solid-phase Radical Reactions and Mechanism of Oxidation of Carbon-chain Polymers // Russian Chemical Reviews. 1978. Vol. 47. No. 6. pp. 572-586.
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TY - JOUR
DO - 10.1070/RC1978v047n06ABEH002239
UR - https://rcr.colab.ws/publications/10.1070/RC1978v047n06ABEH002239
TI - Solid-phase Radical Reactions and Mechanism of Oxidation of Carbon-chain Polymers
T2 - Russian Chemical Reviews
AU - Denisov, Evgenii Timofeevich
PY - 1978
DA - 1977/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 572-586
IS - 6
VL - 47
ER -
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@article{1978_Denisov,
author = {Evgenii Timofeevich Denisov},
title = {Solid-phase Radical Reactions and Mechanism of Oxidation of Carbon-chain Polymers},
journal = {Russian Chemical Reviews},
year = {1978},
volume = {47},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1978v047n06ABEH002239},
number = {6},
pages = {572--586},
doi = {10.1070/RC1978v047n06ABEH002239}
}
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Denisov, Evgenii Timofeevich. “Solid-phase Radical Reactions and Mechanism of Oxidation of Carbon-chain Polymers.” Russian Chemical Reviews, vol. 47, no. 6, Nov. 1978, pp. 572-586. https://rcr.colab.ws/publications/10.1070/RC1978v047n06ABEH002239.
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Abstract

Analysis of recent results on the kinetics of the oxidation of model hydrocarbons and carbon-chain polymers in solution and in the solid phase emphasises the common character of the oxidation mechanisms in liquid and solid phases. Detailed consideration is given to specific features of the solid-phase oxidation of polymers consequent on their high molecular mass, inhomogeneity in the solid state, the influence of molecular mobility on the kinetics of radical reactions, and the migration of free electrons. A list of 104 references is included.