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Topological Principles of the Analysis of Binary Statistical Copolymerisation

Vitalii Alekseevich Myagchenkov 1
Vitalii Alekseevich Myagchenkov
, 
Sergei Yakovlevich Frenkel' 2
Sergei Yakovlevich Frenkel'
1 Kazan Institute for Chemical Technology
2 Institute of Macromolecular Compounds of the Academy of Sciences of the USSR, Leningrad
Published 30 November 1977
Communication , Volume 47, Issue 7, 665-683
8
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Myagchenkov V. A., Frenkel' S. Y. Topological Principles of the Analysis of Binary Statistical Copolymerisation // Russian Chemical Reviews. 1978. Vol. 47. No. 7. pp. 665-683.
GOST all authors (up to 50)
Myagchenkov V. A., Frenkel' S. Y. Topological Principles of the Analysis of Binary Statistical Copolymerisation // Russian Chemical Reviews. 1978. Vol. 47. No. 7. pp. 665-683.
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TY - JOUR
DO - 10.1070/RC1978v047n07ABEH002245
UR - https://rcr.colab.ws/publications/10.1070/RC1978v047n07ABEH002245
TI - Topological Principles of the Analysis of Binary Statistical Copolymerisation
T2 - Russian Chemical Reviews
AU - Myagchenkov, Vitalii Alekseevich
AU - Frenkel', Sergei Yakovlevich
PY - 1978
DA - 1977/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 665-683
IS - 7
VL - 47
ER -
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@article{1978_Myagchenkov,
author = {Vitalii Alekseevich Myagchenkov and Sergei Yakovlevich Frenkel'},
title = {Topological Principles of the Analysis of Binary Statistical Copolymerisation},
journal = {Russian Chemical Reviews},
year = {1978},
volume = {47},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1978v047n07ABEH002245},
number = {7},
pages = {665--683},
doi = {10.1070/RC1978v047n07ABEH002245}
}
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Myagchenkov, Vitalii Alekseevich, and Sergei Yakovlevich Frenkel'. “Topological Principles of the Analysis of Binary Statistical Copolymerisation.” Russian Chemical Reviews, vol. 47, no. 7, Nov. 1978, pp. 665-683. https://rcr.colab.ws/publications/10.1070/RC1978v047n07ABEH002245.
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Abstract

The criteria for the estimation of the characteristics of binary statistical copolymerisation, namely composition, curves for distribution with respect to composition, chemical structure of macromolecules, and parameters of the quantitative estimate of inhomogeneity with respect to composition, are examined on the basis of the most general model of such a process. It is suggested that all copolymeric systems be divided into four classes: (1) classical; (2) classical subject to certain boundary conditions; (3) "unusual" systems of the first kind; (4) "unusual" systems of the second kind ("anomalous" systems).
The principles described are illustrated by the analysis of a number of specific models (heterophase copolymerisation, copolymerisation of ionogenic monomers in ionising media, copolymerisation of partly complexed monomers, copolymerisation complicated by reactions involving chain transfer to macromolecules or by depolymerisation reactions, etc.).
The bibliography includes 136 references.