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The Use of Spin-trapping in the Study of the Mechanisms of Radical Processes

V E Zubarev 1
V E Zubarev
, 
Vladilen Nikitich Belevskii 1
Vladilen Nikitich Belevskii
, 
Lenar Timofeevich Bugaenko 1
Lenar Timofeevich Bugaenko
1 Lomonosov Moscow State University, Faculty of Chemistry
10.1070/RC1979v048n08ABEH002407
Published 30 November 1978
Communication , Volume 48, Issue 8, 729-745
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Zubarev V. E., Belevskii V. N., Bugaenko L. T. The Use of Spin-trapping in the Study of the Mechanisms of Radical Processes // Russian Chemical Reviews. 1979. Vol. 48. No. 8. pp. 729-745.
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Zubarev V. E., Belevskii V. N., Bugaenko L. T. The Use of Spin-trapping in the Study of the Mechanisms of Radical Processes // Russian Chemical Reviews. 1979. Vol. 48. No. 8. pp. 729-745.
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TY - JOUR
DO - 10.1070/RC1979v048n08ABEH002407
UR - https://rcr.colab.ws/publications/10.1070/RC1979v048n08ABEH002407
TI - The Use of Spin-trapping in the Study of the Mechanisms of Radical Processes
T2 - Russian Chemical Reviews
AU - Zubarev, V E
AU - Belevskii, Vladilen Nikitich
AU - Bugaenko, Lenar Timofeevich
PY - 1979
DA - 1978/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 729-745
IS - 8
VL - 48
ER -
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@article{1979_Zubarev,
author = {V E Zubarev and Vladilen Nikitich Belevskii and Lenar Timofeevich Bugaenko},
title = {The Use of Spin-trapping in the Study of the Mechanisms of Radical Processes},
journal = {Russian Chemical Reviews},
year = {1979},
volume = {48},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1979v048n08ABEH002407},
number = {8},
pages = {729--745},
doi = {10.1070/RC1979v048n08ABEH002407}
}
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Zubarev, V. E., et al. “The Use of Spin-trapping in the Study of the Mechanisms of Radical Processes.” Russian Chemical Reviews, vol. 48, no. 8, Nov. 1979, pp. 729-745. https://rcr.colab.ws/publications/10.1070/RC1979v048n08ABEH002407.
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Abstract

The review is devoted to the spin-trapping method developed in recent years and used to identify short-lived radicals (mainly in liquid phase) and to investigate the mechanisms of their reactions. Unstable radicals are accepted by a spin-trapping agent with formation of a fairly stable free radical which carries information about its short-lived precursor. The EPR spectra of the resulting spin adducts can be recorded in the liquid phase and are as a rule well resolved. The properties of various spin-trapping agents are described in detail and tables of the parameters of the EPR spectra of the adducts of spin-trapping agents with the trapped radicals are presented. The application of the spin-trapping method in the study of the mechanisms of radical processes in various fields of chemistry is considered.
The bibliography includes 161 references.