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The Influence of the Solvent on the Rates of Chain Propagation and Termination Reactions in Radical Polymerisation

Vladimir Fedorovich Gromov 1
Vladimir Fedorovich Gromov
, 
P M Khomikovskii 1
P M Khomikovskii
1 Karpov Institute of Physical Chemistry, Moscow
10.1070/RC1979v048n11ABEH002428
Published 30 November 1978
Communication , Volume 48, Issue 11, 1040-1054
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Gromov V. F., Khomikovskii P. M. The Influence of the Solvent on the Rates of Chain Propagation and Termination Reactions in Radical Polymerisation // Russian Chemical Reviews. 1979. Vol. 48. No. 11. pp. 1040-1054.
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Gromov V. F., Khomikovskii P. M. The Influence of the Solvent on the Rates of Chain Propagation and Termination Reactions in Radical Polymerisation // Russian Chemical Reviews. 1979. Vol. 48. No. 11. pp. 1040-1054.
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TY - JOUR
DO - 10.1070/RC1979v048n11ABEH002428
UR - https://rcr.colab.ws/publications/10.1070/RC1979v048n11ABEH002428
TI - The Influence of the Solvent on the Rates of Chain Propagation and Termination Reactions in Radical Polymerisation
T2 - Russian Chemical Reviews
AU - Gromov, Vladimir Fedorovich
AU - Khomikovskii, P M
PY - 1979
DA - 1978/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1040-1054
IS - 11
VL - 48
ER -
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@article{1979_Gromov,
author = {Vladimir Fedorovich Gromov and P M Khomikovskii},
title = {The Influence of the Solvent on the Rates of Chain Propagation and Termination Reactions in Radical Polymerisation},
journal = {Russian Chemical Reviews},
year = {1979},
volume = {48},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1979v048n11ABEH002428},
number = {11},
pages = {1040--1054},
doi = {10.1070/RC1979v048n11ABEH002428}
}
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Gromov, Vladimir Fedorovich, and P M Khomikovskii. “The Influence of the Solvent on the Rates of Chain Propagation and Termination Reactions in Radical Polymerisation.” Russian Chemical Reviews, vol. 48, no. 11, Nov. 1979, pp. 1040-1054. https://rcr.colab.ws/publications/10.1070/RC1979v048n11ABEH002428.
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Abstract

The influence of the solvent on the rate of radical polymerisation and copolymerisation, observed and investigated in the last ten years and caused mainly by a change in the rate of the elementary chain propagation reaction, is discussed. The published data on the polymerisation and copolymerisation of a number of monomers in solvents of different types are surveyed. Attention is drawn to the fact that the greatest effects are observed for polar monomers, particularly for water-soluble monomers in an aqueous medium. The causes of the change in the overall rate of reaction, the constants kp, and the copolymerisation constants for different monomers are examined.
The bibliography includes 104 references.