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Spectroscopic Study of π-Acceptor Effects in Compounds of Silicon Subgroup Elements

Aleksei Nikolaevich Egorochkin 1
Aleksei Nikolaevich Egorochkin
, 
Stanislav Yakovlevich Khorshev 1
Stanislav Yakovlevich Khorshev
1 Institute of Chemistry, Academy of Sciences of the USSR, Gor'kii
10.1070/RC1980v049n09ABEH002508
Published 30 November 1979
Communication , Volume 49, Issue 9, 820-832
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Egorochkin A. N., Khorshev S. Y. Spectroscopic Study of π-Acceptor Effects in Compounds of Silicon Subgroup Elements // Russian Chemical Reviews. 1980. Vol. 49. No. 9. pp. 820-832.
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Egorochkin A. N., Khorshev S. Y. Spectroscopic Study of π-Acceptor Effects in Compounds of Silicon Subgroup Elements // Russian Chemical Reviews. 1980. Vol. 49. No. 9. pp. 820-832.
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TY - JOUR
DO - 10.1070/RC1980v049n09ABEH002508
UR - https://rcr.colab.ws/publications/10.1070/RC1980v049n09ABEH002508
TI - Spectroscopic Study of π-Acceptor Effects in Compounds of Silicon Subgroup Elements
T2 - Russian Chemical Reviews
AU - Egorochkin, Aleksei Nikolaevich
AU - Khorshev, Stanislav Yakovlevich
PY - 1980
DA - 1979/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 820-832
IS - 9
VL - 49
ER -
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@article{1980_Egorochkin,
author = {Aleksei Nikolaevich Egorochkin and Stanislav Yakovlevich Khorshev},
title = {Spectroscopic Study of π-Acceptor Effects in Compounds of Silicon Subgroup Elements},
journal = {Russian Chemical Reviews},
year = {1980},
volume = {49},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1980v049n09ABEH002508},
number = {9},
pages = {820--832},
doi = {10.1070/RC1980v049n09ABEH002508}
}
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Egorochkin, Aleksei Nikolaevich, and Stanislav Yakovlevich Khorshev. “Spectroscopic Study of π-Acceptor Effects in Compounds of Silicon Subgroup Elements.” Russian Chemical Reviews, vol. 49, no. 9, Nov. 1980, pp. 820-832. https://rcr.colab.ws/publications/10.1070/RC1980v049n09ABEH002508.
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Abstract

The general state of research into the π-acceptor properties of silicon subgroup elements (E) by spectroscopic methods is examined and the data obtained are surveyed. It is shown that the π-acceptor properties are weakened with increase of the atomic number of the element E, and the analogy between these properties and the conjugation effect in unsaturated carbon compounds is traced. The widespread interpretation of π-acceptor properties of these elements as a manifestation of the effect of the dπ–pπ interaction is justified.
The bibliography includes 167 references.