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α-Ketophosphonic Acid Esters – Synthesis, Structure, and Reactions

Yurii Andreevich Zhdanov 1, 2
Yurii Andreevich Zhdanov
, 
L A Uzlova 1, 2
L A Uzlova
, 
Zoya Ivanovna Glebova 1, 2
Zoya Ivanovna Glebova
1 Rostov State University
2 Research Institute of Physical and Organic Chemistry, Rostov State University
10.1070/RC1980v049n09ABEH002510
Published 30 November 1979
Communication , Volume 49, Issue 9, 843-853
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Zhdanov Y. A., Uzlova L. A., Glebova Z. I. α-Ketophosphonic Acid Esters – Synthesis, Structure, and Reactions // Russian Chemical Reviews. 1980. Vol. 49. No. 9. pp. 843-853.
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Zhdanov Y. A., Uzlova L. A., Glebova Z. I. α-Ketophosphonic Acid Esters – Synthesis, Structure, and Reactions // Russian Chemical Reviews. 1980. Vol. 49. No. 9. pp. 843-853.
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TY - JOUR
DO - 10.1070/RC1980v049n09ABEH002510
UR - https://rcr.colab.ws/publications/10.1070/RC1980v049n09ABEH002510
TI - α-Ketophosphonic Acid Esters – Synthesis, Structure, and Reactions
T2 - Russian Chemical Reviews
AU - Zhdanov, Yurii Andreevich
AU - Uzlova, L A
AU - Glebova, Zoya Ivanovna
PY - 1980
DA - 1979/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 843-853
IS - 9
VL - 49
ER -
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@article{1980_Zhdanov,
author = {Yurii Andreevich Zhdanov and L A Uzlova and Zoya Ivanovna Glebova},
title = {α-Ketophosphonic Acid Esters – Synthesis, Structure, and Reactions},
journal = {Russian Chemical Reviews},
year = {1980},
volume = {49},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1980v049n09ABEH002510},
number = {9},
pages = {843--853},
doi = {10.1070/RC1980v049n09ABEH002510}
}
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Zhdanov, Yurii Andreevich, et al. “α-Ketophosphonic Acid Esters – Synthesis, Structure, and Reactions.” Russian Chemical Reviews, vol. 49, no. 9, Nov. 1980, pp. 843-853. https://rcr.colab.ws/publications/10.1070/RC1980v049n09ABEH002510.
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Abstract

Studies on the synthesis and properties of α-ketophosphonic acid esters (KPE) – a class of highly reactive organophosphorus compounds – are surveyed. Data are presented concerning instances of the anomalous course of the process in the synthesis of KPE by the Arbuzov reaction. The reactions of KPE with nucleophiles, including those which lead to the rupture of the phosphorus–carbon bond, are examined in detail. The problems of the stereochemistry of KPE are dealt with briefly.
The bibliography includes 162 references.