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The Mechanism of the Catalytic Polymerisation of Olefins Based on the Number of Active Centres and the Rate Constants for Individual Stages

Vladimir Aleksandrovich Zakharov 1
Vladimir Aleksandrovich Zakharov
, 
Gennadii Dmitrievich Bukatov 1
Gennadii Dmitrievich Bukatov
, 
Yurii Ivanovich Ermakov 1
Yurii Ivanovich Ermakov
1 Institute of Catalysis Siberian Branch of the Russian Academy of Sciences, Novosibirsk
10.1070/RC1980v049n11ABEH002530
Published 30 November 1979
Communication , Volume 49, Issue 11, 1097-1111
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Zakharov V. A., Bukatov G. D., Ermakov Y. I. The Mechanism of the Catalytic Polymerisation of Olefins Based on the Number of Active Centres and the Rate Constants for Individual Stages // Russian Chemical Reviews. 1980. Vol. 49. No. 11. pp. 1097-1111.
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Zakharov V. A., Bukatov G. D., Ermakov Y. I. The Mechanism of the Catalytic Polymerisation of Olefins Based on the Number of Active Centres and the Rate Constants for Individual Stages // Russian Chemical Reviews. 1980. Vol. 49. No. 11. pp. 1097-1111.
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TY - JOUR
DO - 10.1070/RC1980v049n11ABEH002530
UR - https://rcr.colab.ws/publications/10.1070/RC1980v049n11ABEH002530
TI - The Mechanism of the Catalytic Polymerisation of Olefins Based on the Number of Active Centres and the Rate Constants for Individual Stages
T2 - Russian Chemical Reviews
AU - Zakharov, Vladimir Aleksandrovich
AU - Bukatov, Gennadii Dmitrievich
AU - Ermakov, Yurii Ivanovich
PY - 1980
DA - 1979/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1097-1111
IS - 11
VL - 49
ER -
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@article{1980_Zakharov,
author = {Vladimir Aleksandrovich Zakharov and Gennadii Dmitrievich Bukatov and Yurii Ivanovich Ermakov},
title = {The Mechanism of the Catalytic Polymerisation of Olefins Based on the Number of Active Centres and the Rate Constants for Individual Stages},
journal = {Russian Chemical Reviews},
year = {1980},
volume = {49},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1980v049n11ABEH002530},
number = {11},
pages = {1097--1111},
doi = {10.1070/RC1980v049n11ABEH002530}
}
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Zakharov, Vladimir Aleksandrovich, et al. “The Mechanism of the Catalytic Polymerisation of Olefins Based on the Number of Active Centres and the Rate Constants for Individual Stages.” Russian Chemical Reviews, vol. 49, no. 11, Nov. 1980, pp. 1097-1111. https://rcr.colab.ws/publications/10.1070/RC1980v049n11ABEH002530.
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Abstract

New data on the numbers of active centres and rate constants for individual stages in the catalytic polymerisation of olefins in the presence of two-component catalysts, obtained by the method of selective radioactive inhibitors, are considered. Certain general aspects of the mechanism of the catalytic polymerisation of olefins are examined on the basis of these data as well as the results of the study of one-component organometallic catalysts and quantum-chemical investigations of the propagation reaction.
The bibliography includes 102 references.