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Kinetics and Mechanism of the Reaction of Ozone with Double Bonds

Stanislav Dmitrievich Razumovskii 1
Stanislav Dmitrievich Razumovskii
, 
Gennadii Efremovich Zaikov 1
Gennadii Efremovich Zaikov
1 Institute of Chemical Physics of the USSR Academy of Sciences, Moscow
Published 30 November 1979
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Razumovskii S. D., Zaikov G. E. Kinetics and Mechanism of the Reaction of Ozone with Double Bonds // Russian Chemical Reviews. 1980. Vol. 49. No. 12. pp. 1163-1180.
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Razumovskii S. D., Zaikov G. E. Kinetics and Mechanism of the Reaction of Ozone with Double Bonds // Russian Chemical Reviews. 1980. Vol. 49. No. 12. pp. 1163-1180.
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TY - JOUR
DO - 10.1070/RC1980v049n12ABEH002535
UR - https://rcr.colab.ws/publications/10.1070/RC1980v049n12ABEH002535
TI - Kinetics and Mechanism of the Reaction of Ozone with Double Bonds
T2 - Russian Chemical Reviews
AU - Razumovskii, Stanislav Dmitrievich
AU - Zaikov, Gennadii Efremovich
PY - 1980
DA - 1979/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1163-1180
IS - 12
VL - 49
ER -
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BibTex (up to 50 authors)
@article{1980_Razumovskii,
author = {Stanislav Dmitrievich Razumovskii and Gennadii Efremovich Zaikov},
title = {Kinetics and Mechanism of the Reaction of Ozone with Double Bonds},
journal = {Russian Chemical Reviews},
year = {1980},
volume = {49},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1980v049n12ABEH002535},
number = {12},
pages = {1163--1180},
doi = {10.1070/RC1980v049n12ABEH002535}
}
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Razumovskii, Stanislav Dmitrievich, and Gennadii Efremovich Zaikov. “Kinetics and Mechanism of the Reaction of Ozone with Double Bonds.” Russian Chemical Reviews, vol. 49, no. 12, Nov. 1980, pp. 1163-1180. https://rcr.colab.ws/publications/10.1070/RC1980v049n12ABEH002535.
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Abstract

Analysis of the results of recent studies has shown that the reaction of ozone with the double bonds of organic compounds apparently takes place not by a synchronous addition mechanism but through a reversible stage involving the formation of an intermediate complex of ozone with the double bond. The subsequent stages of the reaction involve the formation of a primary ozonide, its decomposition into two fragments, their combination, and a number of other transformations. The properties of the intermediate products, the relationship between the structure of the original alkenes and their reactivity towards ozone, the influence of the nature of the solvent on the direction and rate of the reaction, and the practical application of the reaction of ozone with double bonds in research and chemical technology have been examined. The bibliography contains 205 references.