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The Mechanism of the Electrophilic Addition of Halogens to a Multiple Bond

Kirill Aleksandrovich V'yunov 1
Kirill Aleksandrovich V'yunov
, 
Anatolii Iosifovich Ginak 1
Anatolii Iosifovich Ginak
1 Leningrad Technological Institute
10.1070/RC1981v050n02ABEH002552
Published 30 November 1980
Communication , Volume 50, Issue 2, 151-163
31
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V'yunov K. A., Ginak A. I. The Mechanism of the Electrophilic Addition of Halogens to a Multiple Bond // Russian Chemical Reviews. 1981. Vol. 50. No. 2. pp. 151-163.
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V'yunov K. A., Ginak A. I. The Mechanism of the Electrophilic Addition of Halogens to a Multiple Bond // Russian Chemical Reviews. 1981. Vol. 50. No. 2. pp. 151-163.
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TY - JOUR
DO - 10.1070/RC1981v050n02ABEH002552
UR - https://rcr.colab.ws/publications/10.1070/RC1981v050n02ABEH002552
TI - The Mechanism of the Electrophilic Addition of Halogens to a Multiple Bond
T2 - Russian Chemical Reviews
AU - V'yunov, Kirill Aleksandrovich
AU - Ginak, Anatolii Iosifovich
PY - 1981
DA - 1980/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 151-163
IS - 2
VL - 50
ER -
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@article{1981_V'yunov,
author = {Kirill Aleksandrovich V'yunov and Anatolii Iosifovich Ginak},
title = {The Mechanism of the Electrophilic Addition of Halogens to a Multiple Bond},
journal = {Russian Chemical Reviews},
year = {1981},
volume = {50},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1981v050n02ABEH002552},
number = {2},
pages = {151--163},
doi = {10.1070/RC1981v050n02ABEH002552}
}
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V'yunov, Kirill Aleksandrovich, and Anatolii Iosifovich Ginak. “The Mechanism of the Electrophilic Addition of Halogens to a Multiple Bond.” Russian Chemical Reviews, vol. 50, no. 2, Nov. 1981, pp. 151-163. https://rcr.colab.ws/publications/10.1070/RC1981v050n02ABEH002552.
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Abstract

A systematic account is given of the literature data on the mechanism of the electrophilic halogenation of olefins. Particular attention is devoted to the experimental methods for the investigation of the structures and reactivities of the intermediate unstable adducts produced by the electrophilic addition of the halogen to the multiple bond. The relation between the mechanisms of electrophilic halogenation and other Ad reactions is discussed. Certain aspects of the stereochemistry of the addition of halogens and hypohalites to olefins are examined.
The bibliography includes 192 references.