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The Paramagnetic Probe Method in Adsorption and Catalysis

Vladimir Borisovich Golubev 1
Vladimir Borisovich Golubev
, 
Elena Vadimovna Lunina 1
Elena Vadimovna Lunina
, 
Andrei Konstantinovich Selivanovskii 1
Andrei Konstantinovich Selivanovskii
1 Lomonosov Moscow State University
Published 30 November 1980
Communication , Volume 50, Issue 5, 421-431
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Golubev V. B., Lunina E. V., Selivanovskii A. K. The Paramagnetic Probe Method in Adsorption and Catalysis // Russian Chemical Reviews. 1981. Vol. 50. No. 5. pp. 421-431.
GOST all authors (up to 50)
Golubev V. B., Lunina E. V., Selivanovskii A. K. The Paramagnetic Probe Method in Adsorption and Catalysis // Russian Chemical Reviews. 1981. Vol. 50. No. 5. pp. 421-431.
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TY - JOUR
DO - 10.1070/RC1981v050n05ABEH002625
UR - https://rcr.colab.ws/publications/10.1070/RC1981v050n05ABEH002625
TI - The Paramagnetic Probe Method in Adsorption and Catalysis
T2 - Russian Chemical Reviews
AU - Golubev, Vladimir Borisovich
AU - Lunina, Elena Vadimovna
AU - Selivanovskii, Andrei Konstantinovich
PY - 1981
DA - 1980/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 421-431
IS - 5
VL - 50
ER -
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BibTex (up to 50 authors)
@article{1981_Golubev,
author = {Vladimir Borisovich Golubev and Elena Vadimovna Lunina and Andrei Konstantinovich Selivanovskii},
title = {The Paramagnetic Probe Method in Adsorption and Catalysis},
journal = {Russian Chemical Reviews},
year = {1981},
volume = {50},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1981v050n05ABEH002625},
number = {5},
pages = {421--431},
doi = {10.1070/RC1981v050n05ABEH002625}
}
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Golubev, Vladimir Borisovich, et al. “The Paramagnetic Probe Method in Adsorption and Catalysis.” Russian Chemical Reviews, vol. 50, no. 5, Nov. 1981, pp. 421-431. https://rcr.colab.ws/publications/10.1070/RC1981v050n05ABEH002625.
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Abstract

The application of the paramagnetic probe method to studies of heterogeneous systems is discussed. By analysing the ESR spectra of the adsorbed probes (nitroxyl radicals) information is obtained on the interaction of the probe with the surface of silica gel, aluminium oxide, alumina–silicas, etc. Special attention is paid to the formation of donor–acceptor complexes with co-ordinationally unsaturated cations of the surface, and to the mobility of molecules in the adsorption layer. 53 references.